Kinetics of the gas-phase reactions MOH+ + e- ⇄ M + OH or MO + H (M = Ca or Sr)

A. N. Hayhurst; D. B. Kittelson

doi:10.1039/C39720000422

Kinetics of the gas-phase reactions MOH⁺ + e^- ⇄ M + OH or MO + H (M = Ca or Sr)

A. N. Hayhurst, D. B. Kittelson

Mechanical Engineering

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2 Scopus citations

Abstract

Ionization of alkaline earths in flames is not at equilibrium, the principal ion (MOH⁺ for an alkaline earth M) is produced by the reverse of either of the two processes in the title, with activation energies slightly less than endothermicities, and recombination is bimolecular with a large rate constant (ca. 10^-7 particle^-1 ml s ^-1) displaying a negative temperature coefficient.

Original language	English (US)
Pages (from-to)	422-423
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	0
Issue number	7
DOIs	https://doi.org/10.1039/C39720000422
State	Published - 1972

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Copyright 2007 Elsevier B.V., All rights reserved.

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10.1039/C39720000422

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abstract = "Ionization of alkaline earths in flames is not at equilibrium, the principal ion (MOH+ for an alkaline earth M) is produced by the reverse of either of the two processes in the title, with activation energies slightly less than endothermicities, and recombination is bimolecular with a large rate constant (ca. 10-7 particle-1 ml s -1) displaying a negative temperature coefficient.",

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