Kinetics and mechanism of ethanol dehydration on γ-Al ₂O₃: The critical role of dimer inhibition

Keyphrases

• Ethanol 100%
• Ethanol Dehydration 100%
• Aluminum Oxide 100%
• Ethanol-water 80%
• Dimethyl Ether 60%
• Water Dimer 60%
• Deuteration 40%
• Active Sites 40%
• Ether Formation 40%
• Ethylene Synthesis 40%
• Dehydration Reaction 40%
• Water Pressure 40%
• Ether Synthesis 40%
• Ethylene 20%
• Zeolite Catalyst 20%
• Steady State 20%
• Proton 20%
• First-order 20%
• C-H Bond 20%
• Pyridine 20%
• Kinetic Isotope Effect 20%
• Desorption 20%
• Bimolecular 20%
• Unimolecular 20%
• Acidic Zeolites 20%
• Competitive Adsorption 20%
• Alumina Surface 20%
• C-O Bond 20%
• Formation Rate 20%
• Olefin Synthesis 20%
• Acidic Alumina 20%
• Transient Study 20%
• Ethoxide 20%
• Chemical Transients 20%
• Alcohol Molecules 20%
• Surface Binding 20%
• On-surface Synthesis 20%

Chemical Engineering

• Dimer 100%
• Ethylene 50%
• Olefin 16%
• Desorption 16%
• Zeolite Catalyst 16%