TY - JOUR
T1 - Kinetics and energetics of a fast polyurethane cure
AU - Lipshitz, Stephen D.
AU - Macosko, Chris
PY - 1977/8
Y1 - 1977/8
N2 - Methods for obtaining kinetic data on bulk polymerizing systems are reviewed, and adiabatic temperature rise is found to be the most useful for fast systems. An adiabatic method is described and used to study the polymerization of poly(ε‐caprolactone triol) with chain‐extended 1,6‐hexane diisocyanate catalyzed with dibutyltin dilaurate.
AB - Methods for obtaining kinetic data on bulk polymerizing systems are reviewed, and adiabatic temperature rise is found to be the most useful for fast systems. An adiabatic method is described and used to study the polymerization of poly(ε‐caprolactone triol) with chain‐extended 1,6‐hexane diisocyanate catalyzed with dibutyltin dilaurate.
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U2 - 10.1002/app.1977.070210803
DO - 10.1002/app.1977.070210803
M3 - Article
AN - SCOPUS:0017526191
SN - 0021-8995
VL - 21
SP - 2029
EP - 2039
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 8
ER -