Isomorphism and pseudosymmetry in 2,6-dichloro-and 2,6-dibromobenzonitrile

Doyle Britton, Wayland E Noland, Matthew J. Pinnow

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The title compounds are isomorphous, with two half-molecules in the asymmetric unit of a monoclinic unit cell in the space group C2/m. For the chloro compound: a = 18.0525 (8), b = 20.7374 (10), c = 3.8334 (2) Å, β = 101.143 (1)°; for the bromo compound: a = 18.2269 (15), b = 21.349 (2), c = 3.9663 (3) Å, β = 101.446 (2)°. The dominant intermolecular interactions are between halogen atoms rather than between halogen and nitrile, as is the case in the corresponding 2,4,6-trihalobenzonitriles. The molecules pack into layers with a fourfold pseudosymmetry. The pseudosymmetry appears to be the consequence of halogen-halogen intermolecular interactions.

Original languageEnglish (US)
Pages (from-to)822-827
Number of pages6
JournalActa Crystallographica Section B: Structural Science
Volume56
Issue number5
DOIs
StatePublished - Oct 2000

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