Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions

Peter I. Dosa; Andreas Schleifenbaum; K. Peter C. Vollhardt

doi:10.5555/ol015519u

Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions

Peter I. Dosa, Andreas Schleifenbaum, K. Peter C. Vollhardt

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

(matrix presented) Flash vacuum pyrolysis (FVP) of linear [3]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on FVP of angular [3]phenylene. A mechanism, supported by a ¹³C labeling study, is proposed to explain these results.

Original language	English (US)
Pages (from-to)	1017-1020
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	7
DOIs	https://doi.org/10.5555/ol015519u
State	Published - Apr 5 2001
Externally published	Yes

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title = "Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions",

abstract = "(matrix presented) Flash vacuum pyrolysis (FVP) of linear [3]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on FVP of angular [3]phenylene. A mechanism, supported by a 13C labeling study, is proposed to explain these results.",

author = "Dosa, {Peter I.} and Andreas Schleifenbaum and Vollhardt, {K. Peter C.}",

year = "2001",

month = apr,

day = "5",

doi = "10.5555/ol015519u",

language = "English (US)",

volume = "3",

pages = "1017--1020",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions

AU - Dosa, Peter I.

AU - Schleifenbaum, Andreas

AU - Vollhardt, K. Peter C.

PY - 2001/4/5

Y1 - 2001/4/5

N2 - (matrix presented) Flash vacuum pyrolysis (FVP) of linear [3]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on FVP of angular [3]phenylene. A mechanism, supported by a 13C labeling study, is proposed to explain these results.

AB - (matrix presented) Flash vacuum pyrolysis (FVP) of linear [3]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on FVP of angular [3]phenylene. A mechanism, supported by a 13C labeling study, is proposed to explain these results.

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DO - 10.5555/ol015519u

M3 - Article

C2 - 11277784

AN - SCOPUS:0000933533

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EP - 1020

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions

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