Isomerism in the adduct of tris(4,4,4,-trifluoro-1-(2-naphthyl)-1,3-butanedionato)europium(iii) with dipyridyl

L. C. Thompson; F. W. Atchison; Victor G Young

doi:10.1016/S0925-8388(98)00436-8

Isomerism in the adduct of tris(4,4,4,-trifluoro-1-(2-naphthyl)-1,3-butanedionato)europium(iii) with dipyridyl

L. C. Thompson, F. W. Atchison, Victor G Young

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The title compound (conveniently abbreviated Eu(TAN)₃·dipy) has been crystallized from a chloroform/2-propanol solvent mixture to give two different forms. These have been characterized by luminescence spectroscopy and by X-ray diffraction. The two forms have different coordination polyhedra which means that they are structural isomers. One of them is best described as bicapped trigonal prismatic and the other, which contains two slightly different molecules, as square antiprismatic.

Original language	English (US)
Pages (from-to)	765-768
Number of pages	4
Journal	Journal of Alloys and Compounds
Volume	275-277
DOIs	https://doi.org/10.1016/S0925-8388(98)00436-8
State	Published - Jul 24 1998

Bibliographical note

Funding Information:
This work was supported by the Undergraduate Research Opportunities Program and the Graduate School of the University of Minnesota.

Keywords

Chloroform/2-propanol mixture
Eu(TAN)·dipy
Luminescence spectroscopy
X-ray diffraction

Publisher link

10.1016/S0925-8388(98)00436-8

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title = "Isomerism in the adduct of tris(4,4,4,-trifluoro-1-(2-naphthyl)-1,3-butanedionato)europium(iii) with dipyridyl",

abstract = "The title compound (conveniently abbreviated Eu(TAN)3·dipy) has been crystallized from a chloroform/2-propanol solvent mixture to give two different forms. These have been characterized by luminescence spectroscopy and by X-ray diffraction. The two forms have different coordination polyhedra which means that they are structural isomers. One of them is best described as bicapped trigonal prismatic and the other, which contains two slightly different molecules, as square antiprismatic.",

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author = "Thompson, {L. C.} and Atchison, {F. W.} and Young, {Victor G}",

note = "Funding Information: This work was supported by the Undergraduate Research Opportunities Program and the Graduate School of the University of Minnesota. ",

year = "1998",

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T1 - Isomerism in the adduct of tris(4,4,4,-trifluoro-1-(2-naphthyl)-1,3-butanedionato)europium(iii) with dipyridyl

AU - Thompson, L. C.

AU - Atchison, F. W.

AU - Young, Victor G

N1 - Funding Information: This work was supported by the Undergraduate Research Opportunities Program and the Graduate School of the University of Minnesota.

PY - 1998/7/24

Y1 - 1998/7/24

N2 - The title compound (conveniently abbreviated Eu(TAN)3·dipy) has been crystallized from a chloroform/2-propanol solvent mixture to give two different forms. These have been characterized by luminescence spectroscopy and by X-ray diffraction. The two forms have different coordination polyhedra which means that they are structural isomers. One of them is best described as bicapped trigonal prismatic and the other, which contains two slightly different molecules, as square antiprismatic.

AB - The title compound (conveniently abbreviated Eu(TAN)3·dipy) has been crystallized from a chloroform/2-propanol solvent mixture to give two different forms. These have been characterized by luminescence spectroscopy and by X-ray diffraction. The two forms have different coordination polyhedra which means that they are structural isomers. One of them is best described as bicapped trigonal prismatic and the other, which contains two slightly different molecules, as square antiprismatic.

KW - Chloroform/2-propanol mixture

KW - Eu(TAN)·dipy

KW - Luminescence spectroscopy

KW - X-ray diffraction

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M3 - Article

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SN - 0925-8388

VL - 275-277

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JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Isomerism in the adduct of tris(4,4,4,-trifluoro-1-(2-naphthyl)-1,3-butanedionato)europium(iii) with dipyridyl

Abstract

Bibliographical note

Keywords

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