Isolation and reactivity of an unusually stable organoselenenyl azide

Kriti Srivastava, Tapash Chakraborty, Harkesh B. Singh, Udai P. Singh, Ray J. Butcher

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The stabilities of a series of isolated covalent selenium(ii) azides such as [2-[1-(3,5-dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole] selenium azide (2a), [2-(4,4-dimethyl-2-oxazolinyl)phenyl]selenenyl azide (3a), [o-(2,6-diisopropylphenyl-iminomethinyl)phenyl]selenenyl azide (4a), [o-(R)-(methylbenzyliminomethinyl)phenyl]selenenyl azide (5a) and o-formylphenylselenenyl azide (6a) are rationalized; also the reactivity of first room temperature stable azide (2a) toward 1,3-cycloaddition has been explored.

Original languageEnglish (US)
Pages (from-to)10137-10141
Number of pages5
JournalDalton Transactions
Volume39
Issue number42
DOIs
StatePublished - Nov 14 2010

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