Iron dissolution and speciation in atmospheric mineral dust: Metal-metal synergistic and antagonistic effects

Eshani Hettiarachchi, Richard L. Reynolds, Harland L. Goldstein, Bruce Moskowitz, Gayan Rubasinghege

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Under acidic atmospheric conditions, iron leached from atmospheric mineral dust may influence the distribution of bioavailable iron at a global scale. However, the effects of non-Fe-containing minerals on iron dissolution remain unknown. This work describes metal-metal synergistic and antagonistic effects on iron dissolution that go beyond aggregation and ionic strength effects in mineral dust mixtures. In this study, we investigated iron mobilization by proton-promoted dissolution in natural mineral dust samples from the Kalahari Desert (SZ1) and Australian Red Dawn event (RO), along with one iron oxide proxy, hematite. The total iron dissolution in natural dust samples highly corresponds with the respective amount of Ti, rather than their particle sizes or Fe contents. The dust sample with high Ti content, SZ1, also showed a higher fraction of dissolved Fe(II), under dark conditions. These observations are in good agreement with the dissolution data for hematite artificially mixed with metal oxides. Total iron dissolution in hematite, mixed with TiO2, is 1.5- and 2-fold higher compared to that of just hematite under dark and light conditions, respectively. However, dissolution of hematite is suppressed when mixed with Al2O3 and CaO. Under dark conditions, furthermore, dissolved Fe(II) fraction is enhanced for hematite when mixed with TiO2 compared to that of other mixtures or hematite alone. Yet, dissolved Fe(II) is lower in hematite mixed with TiO2 under light conditions compared to that of hematite alone, suggesting photo-oxidation of Fe(II) by reactive oxygen species, such as OH radicals.

Original languageEnglish (US)
Pages (from-to)417-423
Number of pages7
JournalAtmospheric Environment
Volume187
DOIs
StatePublished - Aug 2018

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hematite
dissolution
dust
iron
metal
mineral
effect
photooxidation
iron oxide
mobilization
desert
particle size
fold

Keywords

  • Bioavailable iron
  • Iron dissolution
  • Mineralogy effects
  • Photochemistry
  • Redox cycling
  • Titanium dioxide

Cite this

Iron dissolution and speciation in atmospheric mineral dust : Metal-metal synergistic and antagonistic effects. / Hettiarachchi, Eshani; Reynolds, Richard L.; Goldstein, Harland L.; Moskowitz, Bruce; Rubasinghege, Gayan.

In: Atmospheric Environment, Vol. 187, 08.2018, p. 417-423.

Research output: Contribution to journalArticle

Hettiarachchi, Eshani ; Reynolds, Richard L. ; Goldstein, Harland L. ; Moskowitz, Bruce ; Rubasinghege, Gayan. / Iron dissolution and speciation in atmospheric mineral dust : Metal-metal synergistic and antagonistic effects. In: Atmospheric Environment. 2018 ; Vol. 187. pp. 417-423.
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