Introduction of the halonitromethyl framework into aromatic rings via a XeF2 mediated radical process

Valery K. Brel, Anatoly S. Koz'min, Ivan V. Martynov, Viktor I. Uvarov, Nikolai S. Zefirov, Viktor V. Zhdankin, Peter J. Stang

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Reaction of difluoronitro- and fluorochloronitroacetic acids with aromatic substrates in the presence of XeF2 results in alkylation of the aromatic ring by the O2NF2C· and O2NFCIC· radicals.

Original languageEnglish (US)
Pages (from-to)4799-4800
Number of pages2
JournalTetrahedron Letters
Volume31
Issue number33
DOIs
StatePublished - 1990
Externally publishedYes

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