Intramolecular aminocyanation of alkenes by N-CN bond cleavage

Keyphrases

• Alkenes 100%
• Bond Cleavage 100%
• Aminocyanation 100%
• Lewis Acids 60%
• Sulfonamide Antibiotics 60%
• Nitrile Group 60%
• Vicinal 40%
• Excellent Yields 40%
• Sulfonyl 40%
• Atom Economy 40%
• Acid-promoted 40%
• Cyanamide 40%
• Dissociation 20%
• Labeling Experiment 20%
• Regioselectivity 20%
• Metal-free 20%
• Nitriles 20%
• Under Air 20%
• Crossing Experiment 20%
• Double Crossover 20%
• Complementary Strategy 20%
• Indoline 20%
• Intramolecular Cyclization 20%
• Tetrahydroquinoline 20%
• B(C6F5)3 20%
• Alkene Difunctionalization 20%
• Mechanistic Studies 20%
• Heterocycles 20%

Chemistry

• Alkene 100%
• Nitrile 66%
• Sulfonamide 50%
• Lewis Acid 50%
• Cyanamide 33%
• Label 16%
• Mechanistic Study 16%
• Intramolecular Cyclization 16%
• Heterocyclic Compound 16%
• Indolines 16%