Abstract
We calculate the vibrational-rotational nonequilibrium effects on the rate constant for a fast second-order reaction, and we show that they are small under typical experimental conditions. We also discuss the conditions under which such effects might be expected to be larger.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5-7 |
| Number of pages | 3 |
| Journal | Journal of physical chemistry |
| Volume | 89 |
| Issue number | 1 |
| DOIs | |
| State | Published - 1985 |