Internal-state nonequilibrium effects for a fast, second-order reaction

Carmay Lim; Donald G Truhlar

doi:10.1021/j100247a003

Internal-state nonequilibrium effects for a fast, second-order reaction

Carmay Lim, Donald G Truhlar

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We calculate the vibrational-rotational nonequilibrium effects on the rate constant for a fast second-order reaction, and we show that they are small under typical experimental conditions. We also discuss the conditions under which such effects might be expected to be larger.

Original language	English (US)
Pages (from-to)	5-7
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	89
Issue number	1
DOIs	https://doi.org/10.1021/j100247a003
State	Published - Jan 1 1985

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abstract = "We calculate the vibrational-rotational nonequilibrium effects on the rate constant for a fast second-order reaction, and we show that they are small under typical experimental conditions. We also discuss the conditions under which such effects might be expected to be larger.",

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Internal-state nonequilibrium effects for a fast, second-order reaction

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