Internal-state nonequilibrium effects for a fast, second-order reaction

Carmay Lim, Donald G Truhlar

Research output: Contribution to journalArticlepeer-review

11 Scopus citations


We calculate the vibrational-rotational nonequilibrium effects on the rate constant for a fast second-order reaction, and we show that they are small under typical experimental conditions. We also discuss the conditions under which such effects might be expected to be larger.

Original languageEnglish (US)
Pages (from-to)5-7
Number of pages3
JournalJournal of Physical Chemistry
Issue number1
StatePublished - Jan 1 1985


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