Intermediates in reactions of copper(I) Complexes with N-Oxides: from the formation of stable adducts to Oxo Transfer

Sungjun Hong; Aaio K. Gupta; William B. Tolman

doi:10.1021/ic900435p

Intermediates in reactions of copper(I) Complexes with N-Oxides: from the formation of stable adducts to Oxo Transfer

Sungjun Hong, Aaio K. Gupta, William B. Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) Noxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving oxo transfer.

Original language	English (US)
Pages (from-to)	6323-6325
Number of pages	3
Journal	Inorganic chemistry
Volume	48
Issue number	14
DOIs	https://doi.org/10.1021/ic900435p
State	Published - Jul 20 2009

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abstract = "Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) Noxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving oxo transfer.",

author = "Sungjun Hong and Gupta, {Aaio K.} and Tolman, {William B.}",

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AU - Tolman, William B.

PY - 2009/7/20

Y1 - 2009/7/20

N2 - Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) Noxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving oxo transfer.

AB - Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) Noxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving oxo transfer.

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Intermediates in reactions of copper(I) Complexes with N-Oxides: from the formation of stable adducts to Oxo Transfer

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