Intermediates in reactions of copper(I) Complexes with N-Oxides: from the formation of stable adducts to Oxo Transfer

Sungjun Hong, Aaio K. Gupta, William B. Tolman

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) Noxide adducts, aryl substituent hydroxylation, and bis(μ-oxo)dicopper complex formation via a route involving oxo transfer.

Original languageEnglish (US)
Pages (from-to)6323-6325
Number of pages3
JournalInorganic chemistry
Volume48
Issue number14
DOIs
StatePublished - Jul 20 2009

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