Intermediacy of copper(i) under oxidative conditions in the aerobic copper-catalyzed decarboxylative thiolation of benzoic acids

Keyphrases

• Phen 100%
• Aerobic 100%
• Oxidative Conditions 100%
• Thiolation 100%
• Copper-catalyzed 100%
• Benzoic Acid 100%
• Decarboxylative 100%
• Cu(II) 33%
• Stoichiometric Reaction 16%
• Induction Period 16%
• Arenethiols 16%
• Copper(I) Carboxylate 16%
• Spectroscopic Studies 8%
• Synthesis Study 8%
• Well-defined 8%
• Catalytic Reaction 8%
• Resting State 8%
• Reaction Pathway 8%
• First-order 8%
• Thiolate 8%
• Disulfide 8%
• Copper Complex 8%
• Reaction Conditions 8%
• 1,10-Phenanthroline 8%
• Zero Order 8%
• Copper(I) Complexes 8%
• Cu(II) Complex 8%
• Reactivity Studies 8%
• Kinetic Measurements 8%
• Oxidative Cleavage 8%
• Decarboxylation 8%
• 4-nitrobenzoic Acid 8%
• Copper(I) 8%
• In Situ Generated 8%
• Catalytic Turnover 8%
• Measurement Support 8%
• CuOx 8%
• In Situ Reduction 8%
• C-S Coupling Reaction 8%
• Copper(II) Carboxylates 8%
• Mechanistic Studies 8%

Chemistry

• Nitrogen Dioxide 100%
• Benzoic Acid 100%
• thiolation 100%
• Carboxylic Acid 42%
• Coupling Reaction 14%
• Mechanistic Study 14%
• Decarboxylation 14%
• 1,10-phenanthroline 14%
• 2-Nitrobenzoic Acid 14%
• Kinetics Measurement 14%
• Oxidative Elimination Reaction 14%
• Disulfide 14%
• Catalytic Reaction 14%
• formation 14%