Interaction of fischer carbene complexes of the type W(CO)5[C(OMe)R] (R = CH3, C2H5) with acetylenes

David W. Macomber

doi:10.1021/om00088a024

Interaction of fischer carbene complexes of the type W(CO)₅[C(OMe)R] (R = CH₃, C₂H₅) with acetylenes

David W. Macomber

Medicine - General Internal Medicine

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

W(CO)₅[C(OMe)CH₂R¹] (R¹ = H, CH₃) reacts with PhC₂R₂ (R₂ = Ph, CH₃) in toluene at 100 °C to give vinyl ethers and enones. The formation of these products can be explained by an exocyclic β-hydride elimination reaction of a metallacyclobutene intermediate.

Original language	English (US)
Pages (from-to)	1589-1591
Number of pages	3
Journal	Organometallics
Volume	3
Issue number	10
DOIs	https://doi.org/10.1021/om00088a024
State	Published - Dec 1984

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10.1021/om00088a024

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title = "Interaction of fischer carbene complexes of the type W(CO)5[C(OMe)R] (R = CH3, C2H5) with acetylenes",

abstract = "W(CO)5[C(OMe)CH2R1] (R1 = H, CH3) reacts with PhC2R2 (R2 = Ph, CH3) in toluene at 100 °C to give vinyl ethers and enones. The formation of these products can be explained by an exocyclic β-hydride elimination reaction of a metallacyclobutene intermediate.",

author = "Macomber, {David W.}",

year = "1984",

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T1 - Interaction of fischer carbene complexes of the type W(CO)5[C(OMe)R] (R = CH3, C2H5) with acetylenes

AU - Macomber, David W.

PY - 1984/12

Y1 - 1984/12

N2 - W(CO)5[C(OMe)CH2R1] (R1 = H, CH3) reacts with PhC2R2 (R2 = Ph, CH3) in toluene at 100 °C to give vinyl ethers and enones. The formation of these products can be explained by an exocyclic β-hydride elimination reaction of a metallacyclobutene intermediate.

AB - W(CO)5[C(OMe)CH2R1] (R1 = H, CH3) reacts with PhC2R2 (R2 = Ph, CH3) in toluene at 100 °C to give vinyl ethers and enones. The formation of these products can be explained by an exocyclic β-hydride elimination reaction of a metallacyclobutene intermediate.

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Interaction of fischer carbene complexes of the type W(CO)₅[C(OMe)R] (R = CH₃, C₂H₅) with acetylenes

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