Infrared and manometric evidence for the formation of the [Ag(CO) 3]+ complex ion at high PCO

Jeffrey J. Rack; Bahram Moasser; Jerry D. Gargulak; Wayne L Gladfelter; Hans D. Hochheimer; Steven H. Strauss

doi:10.1039/C39940000685

Infrared and manometric evidence for the formation of the [Ag(CO) ₃]⁺ complex ion at high P_CO

Jeffrey J. Rack
, Bahram Moasser
, Jerry D. Gargulak
, Wayne L Gladfelter
, Hans D. Hochheimer
, Steven H. Strauss

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

At high pressures of CO, the Ag⁺ salt of the weekly coordinating anion [Nb(OTeF₅)₆]^- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C₂Cl ₃F₃ solution; the CO ligands can be removed from [Ag(CO)₃][Nb(OTeF₅)₆] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm^-1 for [Ag(CO)₃]⁺, 2198 cm^-1 for [Ag(CO) ₂]⁺, and 2208 cm^-1 for [AgCO]⁺.

Original language	English (US)
Pages (from-to)	685-686
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39940000685
State	Published - 1994

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@article{73f23205c60141abb583f3c5a47882bf,

title = "Infrared and manometric evidence for the formation of the [Ag(CO) 3]+ complex ion at high PCO",

abstract = "At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.",

author = "Rack, \{Jeffrey J.\} and Bahram Moasser and Gargulak, \{Jerry D.\} and Gladfelter, \{Wayne L\} and Hochheimer, \{Hans D.\} and Strauss, \{Steven H.\}",

year = "1994",

doi = "10.1039/C39940000685",

language = "English (US)",

pages = "685--686",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Infrared and manometric evidence for the formation of the [Ag(CO) 3]+ complex ion at high PCO

AU - Rack, Jeffrey J.

AU - Moasser, Bahram

AU - Gargulak, Jerry D.

AU - Gladfelter, Wayne L

AU - Hochheimer, Hans D.

AU - Strauss, Steven H.

PY - 1994

Y1 - 1994

N2 - At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.

AB - At high pressures of CO, the Ag+ salt of the weekly coordinating anion [Nb(OTeF5)6]- takes up three equiv. CO reversibly both in the solid state and in 1,1,2-C2Cl 3F3 solution; the CO ligands can be removed from [Ag(CO)3][Nb(OTeF5)6] under vacuum at 25 °C but none are removed at -78 °C; IR ν(CO) values are 2192 cm-1 for [Ag(CO)3]+, 2198 cm-1 for [Ag(CO) 2]+, and 2208 cm-1 for [AgCO]+.

UR - https://www.scopus.com/pages/publications/37049084584

UR - https://www.scopus.com/pages/publications/37049084584#tab=citedBy

U2 - 10.1039/C39940000685

DO - 10.1039/C39940000685

M3 - Article

AN - SCOPUS:37049084584

SN - 0022-4936

SP - 685

EP - 686

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

Infrared and manometric evidence for the formation of the [Ag(CO) ₃]⁺ complex ion at high P_CO

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