Inductively Coupled Nonthermal Plasma Synthesis of Size-Controlled γ-Al2O3 Nanocrystals

Zichang Xiong, Himashi P. Andaraarachchi, Jacob T. Held, Rick W. Dorn, Yong Jin Jeong, Aaron Rossini, Uwe R. Kortshagen

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Gamma alumina (γ-Al2O3) is widely used as a catalyst and catalytic support due to its high specific surface area and porosity. However, synthesis of γ-Al2O3 nanocrystals is often a complicated process requiring high temperatures or additional post-synthetic steps. Here, we report a single-step synthesis of size-controlled and monodisperse, facetted γ-Al2O3 nanocrystals in an inductively coupled nonthermal plasma reactor using trimethylaluminum and oxygen as precursors. Under optimized conditions, we observed phase-pure, cuboctahedral γ-Al2O3 nanocrystals with defined surface facets. Nuclear magnetic resonance studies revealed that nanocrystal surfaces are populated with AlO6, AlO5 and AlO4 units with clusters of hydroxyl groups. Nanocrystal size tuning was achieved by varying the total reactor pressure yielding particles as small as 3.5 nm, below the predicted thermodynamic stability limit for γ-Al2O3.

Original languageEnglish (US)
Article number1627
JournalNanomaterials
Volume13
Issue number10
DOIs
StatePublished - May 2023

Bibliographical note

Funding Information:
This research was supported by the Army Research Office under MURI Grant W911NF-18-1-0240. Parts of this work were carried out in the Characterization Facility, University of Minnesota, which receives partial support from the US National Science Foundation through the MRSEC (Award Number DMR-2011401) and the NNCI (Award Number ECCS-2025124) programs. Solid-State NMR Spectroscopy (R.D. and A.R.) was supported work was supported by the National Science Foundation under Grant No. CBET-1916809. 19.6 T NMR experiments were performed at the National High Magnetic Field Laboratory. The National High Magnetic Field Laboratory is supported by the National Science Foundation through NSF/DMR-1644779 and the State of Florida.

Publisher Copyright:
© 2023 by the authors.

Keywords

  • gamma alumina
  • nonthermal plasma
  • size-control

MRSEC Support

  • Shared

PubMed: MeSH publication types

  • Journal Article

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