In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework

Sara E. Gilson, Peng Li, Jennifer E.S. Szymanowski, Jacob White, Debmalya Ray, Laura Gagliardi, Omar K. Farha, Peter C. Burns

Research output: Contribution to journalArticle

Abstract

An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-Oyl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.

Original languageEnglish (US)
Pages (from-to)11842-11846
Number of pages5
JournalJournal of the American Chemical Society
Volume141
Issue number30
DOIs
StatePublished - Jul 31 2019

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Neptunium
Raman Spectrum Analysis
Bond length
X-Ray Diffraction
Oxides
Density functional theory
Raman spectroscopy
Wheels
Metals
Topology
X ray diffraction
Atoms

PubMed: MeSH publication types

  • Journal Article

Cite this

In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework. / Gilson, Sara E.; Li, Peng; Szymanowski, Jennifer E.S.; White, Jacob; Ray, Debmalya; Gagliardi, Laura; Farha, Omar K.; Burns, Peter C.

In: Journal of the American Chemical Society, Vol. 141, No. 30, 31.07.2019, p. 11842-11846.

Research output: Contribution to journalArticle

Gilson, Sara E. ; Li, Peng ; Szymanowski, Jennifer E.S. ; White, Jacob ; Ray, Debmalya ; Gagliardi, Laura ; Farha, Omar K. ; Burns, Peter C. / In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 30. pp. 11842-11846.
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AU - Burns, Peter C.

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