Imprint Control of BaTiO3 Thin Films via Chemically Induced Surface Polarization Pinning

Hyungwoo Lee; Tae Heon Kim; Jacob J. Patzner; Haidong Lu; Jung Woo Lee; Hua Zhou; Wansoo Chang; Mahesh K. Mahanthappa; Evgeny Y. Tsymbal; Alexei Gruverman; Chang Beom Eom

doi:10.1021/acs.nanolett.5b05188

Imprint Control of BaTiO₃ Thin Films via Chemically Induced Surface Polarization Pinning

Hyungwoo Lee, Tae Heon Kim, Jacob J. Patzner, Haidong Lu, Jung Woo Lee, Hua Zhou, Wansoo Chang, Mahesh K. Mahanthappa, Evgeny Y. Tsymbal, Alexei Gruverman, Chang Beom Eom

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Surface-adsorbed polar molecules can significantly alter the ferroelectric properties of oxide thin films. Thus, fundamental understanding and controlling the effect of surface adsorbates are crucial for the implementation of ferroelectric thin film devices, such as ferroelectric tunnel junctions. Herein, we report an imprint control of BaTiO₃ (BTO) thin films by chemically induced surface polarization pinning in the top few atomic layers of the water-exposed BTO films. Our studies based on synchrotron X-ray scattering and coherent Bragg rod analysis demonstrate that the chemically induced surface polarization is not switchable but reduces the polarization imprint and improves the bistability of ferroelectric phase in BTO tunnel junctions. We conclude that the chemical treatment of ferroelectric thin films with polar molecules may serve as a simple yet powerful strategy to enhance functional properties of ferroelectric tunnel junctions for their practical applications.

Original language	English (US)
Pages (from-to)	2400-2406
Number of pages	7
Journal	Nano letters
Volume	16
Issue number	4
DOIs	https://doi.org/10.1021/acs.nanolett.5b05188
State	Published - Apr 13 2016

Bibliographical note

Funding Information:
The work at University of Wisconsin-Madison was supported by the US Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-FG02-06ER46327 (fabrication and structural and surface characterization of thin films). The research at University of Nebraska-Lincoln was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-SC0004876 (PFM measurements), and by the National Science Foundation (NSF) through Materials Research Science and Engineering Center (MRSEC) under Grant DMR-1420645 (theoretical modeling).

Publisher Copyright:
© 2016 American Chemical Society.

Keywords

BaTiO
Imprint control
ferroelectric thin films
ferroelectric tunnel junctions
surface chemistry
water adsorption

Publisher link

10.1021/acs.nanolett.5b05188

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@article{86285206c712414c960721bab91fb51b,

title = "Imprint Control of BaTiO3 Thin Films via Chemically Induced Surface Polarization Pinning",

abstract = "Surface-adsorbed polar molecules can significantly alter the ferroelectric properties of oxide thin films. Thus, fundamental understanding and controlling the effect of surface adsorbates are crucial for the implementation of ferroelectric thin film devices, such as ferroelectric tunnel junctions. Herein, we report an imprint control of BaTiO3 (BTO) thin films by chemically induced surface polarization pinning in the top few atomic layers of the water-exposed BTO films. Our studies based on synchrotron X-ray scattering and coherent Bragg rod analysis demonstrate that the chemically induced surface polarization is not switchable but reduces the polarization imprint and improves the bistability of ferroelectric phase in BTO tunnel junctions. We conclude that the chemical treatment of ferroelectric thin films with polar molecules may serve as a simple yet powerful strategy to enhance functional properties of ferroelectric tunnel junctions for their practical applications.",

keywords = "BaTiO, Imprint control, ferroelectric thin films, ferroelectric tunnel junctions, surface chemistry, water adsorption",

author = "Hyungwoo Lee and Kim, {Tae Heon} and Patzner, {Jacob J.} and Haidong Lu and Lee, {Jung Woo} and Hua Zhou and Wansoo Chang and Mahanthappa, {Mahesh K.} and Tsymbal, {Evgeny Y.} and Alexei Gruverman and Eom, {Chang Beom}",

note = "Funding Information: The work at University of Wisconsin-Madison was supported by the US Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-FG02-06ER46327 (fabrication and structural and surface characterization of thin films). The research at University of Nebraska-Lincoln was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-SC0004876 (PFM measurements), and by the National Science Foundation (NSF) through Materials Research Science and Engineering Center (MRSEC) under Grant DMR-1420645 (theoretical modeling). Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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day = "13",

doi = "10.1021/acs.nanolett.5b05188",

language = "English (US)",

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T1 - Imprint Control of BaTiO3 Thin Films via Chemically Induced Surface Polarization Pinning

AU - Lee, Hyungwoo

AU - Kim, Tae Heon

AU - Patzner, Jacob J.

AU - Lu, Haidong

AU - Lee, Jung Woo

AU - Zhou, Hua

AU - Chang, Wansoo

AU - Mahanthappa, Mahesh K.

AU - Tsymbal, Evgeny Y.

AU - Gruverman, Alexei

AU - Eom, Chang Beom

N1 - Funding Information: The work at University of Wisconsin-Madison was supported by the US Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-FG02-06ER46327 (fabrication and structural and surface characterization of thin films). The research at University of Nebraska-Lincoln was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering, under Award DE-SC0004876 (PFM measurements), and by the National Science Foundation (NSF) through Materials Research Science and Engineering Center (MRSEC) under Grant DMR-1420645 (theoretical modeling). Publisher Copyright: © 2016 American Chemical Society.

PY - 2016/4/13

Y1 - 2016/4/13

N2 - Surface-adsorbed polar molecules can significantly alter the ferroelectric properties of oxide thin films. Thus, fundamental understanding and controlling the effect of surface adsorbates are crucial for the implementation of ferroelectric thin film devices, such as ferroelectric tunnel junctions. Herein, we report an imprint control of BaTiO3 (BTO) thin films by chemically induced surface polarization pinning in the top few atomic layers of the water-exposed BTO films. Our studies based on synchrotron X-ray scattering and coherent Bragg rod analysis demonstrate that the chemically induced surface polarization is not switchable but reduces the polarization imprint and improves the bistability of ferroelectric phase in BTO tunnel junctions. We conclude that the chemical treatment of ferroelectric thin films with polar molecules may serve as a simple yet powerful strategy to enhance functional properties of ferroelectric tunnel junctions for their practical applications.

AB - Surface-adsorbed polar molecules can significantly alter the ferroelectric properties of oxide thin films. Thus, fundamental understanding and controlling the effect of surface adsorbates are crucial for the implementation of ferroelectric thin film devices, such as ferroelectric tunnel junctions. Herein, we report an imprint control of BaTiO3 (BTO) thin films by chemically induced surface polarization pinning in the top few atomic layers of the water-exposed BTO films. Our studies based on synchrotron X-ray scattering and coherent Bragg rod analysis demonstrate that the chemically induced surface polarization is not switchable but reduces the polarization imprint and improves the bistability of ferroelectric phase in BTO tunnel junctions. We conclude that the chemical treatment of ferroelectric thin films with polar molecules may serve as a simple yet powerful strategy to enhance functional properties of ferroelectric tunnel junctions for their practical applications.

KW - BaTiO

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KW - surface chemistry

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