Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl Complexes

Keyphrases

• Oxidation State 100%
• Alkyl Complexes 100%
• Nickel(IV) 100%
• Nickel(III) 100%
• Relative Reactivity 66%
• Bond-forming Reactions 66%
• Visible Light 33%
• High-valent 33%
• Bond Formation 33%
• Acetate 33%
• Presence-absence 33%
• Reaction Conditions 33%
• Relative Rate 33%
• Outer-sphere 33%
• Dissociation Kinetics 33%
• Ligand Dissociation 33%
• Electrophilicity 33%
• Tris(pyrazolyl)borate 33%
• Relative Selectivity 33%
• Systematic Comparison 33%
• Reductive Elimination 33%
• Ni(II) Complex 33%
• Tris(pyrazol-1-yl)methane 33%
• Bond-forming 33%
• Sp3 Bonds 33%

Chemistry

• Tris 100%
• Methane 50%
• Electrophilicity 50%
• Reductive Elimination Reaction 50%
• Borate 50%