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Experiments on asymmetric diblock copolymers at temperatures slightly above the order-disorder transition (ODT) temperature indicate the existence of a dense fluid of micelles. Molecular dynamics simulations are used here to identify a higher critical micelle temperature below which micelles appear. The onset of micellization occurs very near where self-consistent field theory predicts an ODT.
|Original language||English (US)|
|Journal||Physical Review Materials|
|State||Published - Sep 9 2021|
Bibliographical noteFunding Information:
This work was supported primarily by NSF Grant No. DMR-1719692, using computational resources provided by the Minnesota Supercomputing Institute (MSI) at the University of Minnesota. Part of this work was carried out with equipment supported by funding from the National Science Foundation through the UMN MRSEC under Award No. DMR-2011401.
© 2021 American Physical Society.
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9/1/20 → 8/31/26
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Data for "Identifying a critical micelle temperature in simulations of disordered asymmetric diblock copolymer melts"