IBX amides: A new family of hypervalent iodine reagents

Viktor Zhdankin; Alexey Y. Koposov; Brian C. Netzel; Nikolai V. Yashin; Brian P. Rempel; Michael J. Ferguson; Rik R. Tykwinski

doi:10.1002/anie.200351018

IBX amides: A new family of hypervalent iodine reagents

Viktor Zhdankin, Alexey Y. Koposov, Brian C. Netzel, Nikolai V. Yashin, Brian P. Rempel, Michael J. Ferguson, Rik R. Tykwinski

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH₃)CO₂CH₃ or CH(CH₂Ph)CO₂CH₃ (in crystal structure shown)).

Original language	English (US)
Pages (from-to)	2194-2196
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	19
DOIs	https://doi.org/10.1002/anie.200351018
State	Published - May 16 2003

Keywords

Alcohols
Hypervalent compounds
Iodine
Oxidation
Synthetic methods

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10.1002/anie.200351018

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title = "IBX amides: A new family of hypervalent iodine reagents",

abstract = "Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).",

keywords = "Alcohols, Hypervalent compounds, Iodine, Oxidation, Synthetic methods",

author = "Viktor Zhdankin and Koposov, \{Alexey Y.\} and Netzel, \{Brian C.\} and Yashin, \{Nikolai V.\} and Rempel, \{Brian P.\} and Ferguson, \{Michael J.\} and Tykwinski, \{Rik R.\}",

year = "2003",

month = may,

day = "16",

doi = "10.1002/anie.200351018",

language = "English (US)",

volume = "42",

pages = "2194--2196",

journal = "Angewandte Chemie - International Edition",

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T1 - IBX amides

T2 - A new family of hypervalent iodine reagents

AU - Zhdankin, Viktor

AU - Koposov, Alexey Y.

AU - Netzel, Brian C.

AU - Yashin, Nikolai V.

AU - Rempel, Brian P.

AU - Ferguson, Michael J.

AU - Tykwinski, Rik R.

PY - 2003/5/16

Y1 - 2003/5/16

N2 - Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).

AB - Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).

KW - Alcohols

KW - Hypervalent compounds

KW - Iodine

KW - Oxidation

KW - Synthetic methods

UR - https://www.scopus.com/pages/publications/0038583812

UR - https://www.scopus.com/inward/citedby.url?scp=0038583812&partnerID=8YFLogxK

U2 - 10.1002/anie.200351018

DO - 10.1002/anie.200351018

M3 - Article

C2 - 12761759

AN - SCOPUS:0038583812

SN - 1433-7851

VL - 42

SP - 2194

EP - 2196

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 19

ER -

IBX amides: A new family of hypervalent iodine reagents

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