IBX amides: A new family of hypervalent iodine reagents

Viktor Zhdankin, Alexey Y. Koposov, Brian C. Netzel, Nikolai V. Yashin, Brian P. Rempel, Michael J. Ferguson, Rik R. Tykwinski

Research output: Contribution to journalArticlepeer-review

76 Scopus citations

Abstract

Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).

Original languageEnglish (US)
Pages (from-to)2194-2196
Number of pages3
JournalAngewandte Chemie - International Edition
Volume42
Issue number19
DOIs
StatePublished - May 16 2003

Keywords

  • Alcohols
  • Hypervalent compounds
  • Iodine
  • Oxidation
  • Synthetic methods

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