Abstract
The chemistry of hypervalent iodine compounds has been widely recognized in the synthetic community. The utilization of hypervalent iodine compounds as stoichiometric reagents as well as catalysts has tremendously been studied in recent decades. Hypervalent iodine (V)-catalyzed reactions are proven to be versatile catalytic systems to access various oxidative transformations. In this review, the versatility of hypervalent iodine (V)catalyzed reactions have been discussed in detail. This review highlights the oxidation of various substrates using catalytic amounts of o-iodoxybenzoic acid (IBX), modified IBX derivatives, o-iodoxybenzenesulfonic acid (IBS), recyclable iodine (V), and non-cyclic/pseudocyclic iodine (V) compounds.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 27-56 |
| Number of pages | 30 |
| Journal | Arkivoc |
| Volume | 2022 |
| Issue number | 7 |
| DOIs | |
| State | Published - 2022 |
| Externally published | Yes |
Bibliographical note
Funding Information:R.K. is thankful to J C Bose University of Science and Technology, YMCA, Seed Grant R&D/SG/2020-21/166 and DST-Haryana for the research grant, HSCSIT/R&D/163. Moreover, T.D. acknowledges support from JSPS KAKENHI Grant Number 19K05466, JST CREST Grant Number JPMJCR20R1, and the Ritsumeikan Global Innovation Research Organization (R-GIRO) project. K.K. acknowledges support from JSPS KAKENHI Grant Number 18H02014. Furthermore, V.V.Z. is thankful to the National Science Foundation (CHE-1759798) for support of his research program on hypervalent iodine chemistry.
Publisher Copyright:
© AUTHOR(S).
Keywords
- Hypervalent compounds
- catalysis
- iodine (V)
- oxidation