Hydrido and chloro gallium and aluminium complexes with the tridentate bis(2-dimethylaminoethyl)amide ligand

Bing Luo; Benjamin E. Kucera; Wayne L Gladfelter

doi:10.1039/b607164c

Hydrido and chloro gallium and aluminium complexes with the tridentate bis(2-dimethylaminoethyl)amide ligand

Bing Luo, Benjamin E. Kucera, Wayne L Gladfelter

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Abstract

Five-coordinate gallium and aluminium dihydrides, H₂Ga[N(CH ₂CH₂NMe₂)₂] (1) and H ₂Al[N(CH₂CH₂NMe₂)₂] (3), were synthesized and found to be volatile and thermally stable. 1 and 3 reacted with H₃Ga(NMe₃) and H₃Al(NMe₃), respectively, to form H₂Ga[N(CH₂CH₂NMe ₂)₂]GaH₃ (2) and H₂Al[N(CH ₂CH₂NMe₂)₂]AlH₃ (4), in which the amido nitrogen bridged between the MH₂ and MH₃ groups (M = Ga or Al). A mixed metal complex, H₂Al[N(CH ₂CH₂NMe₂)₂]GaH₃ (5) was obtained from the reaction of 1 with H₃Al(NMe₃) or 3 with H₃Ga(NMe₃), and a crystal consisting of a mixture of 5 and 2 was structurally characterized. The five-coordinate chloro derivative, Cl₂Ga[N(CH₂CH₂NMe₂)₂] (6), was synthesized and characterized.

Original language	English (US)
Pages (from-to)	4491-4498
Number of pages	8
Journal	Dalton Transactions
Issue number	37
DOIs	https://doi.org/10.1039/b607164c
State	Published - 2006

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@article{95728154653843768b23028e48a61257,

title = "Hydrido and chloro gallium and aluminium complexes with the tridentate bis(2-dimethylaminoethyl)amide ligand",

abstract = "Five-coordinate gallium and aluminium dihydrides, H2Ga[N(CH 2CH2NMe2)2] (1) and H 2Al[N(CH2CH2NMe2)2] (3), were synthesized and found to be volatile and thermally stable. 1 and 3 reacted with H3Ga(NMe3) and H3Al(NMe3), respectively, to form H2Ga[N(CH2CH2NMe 2)2]GaH3 (2) and H2Al[N(CH 2CH2NMe2)2]AlH3 (4), in which the amido nitrogen bridged between the MH2 and MH3 groups (M = Ga or Al). A mixed metal complex, H2Al[N(CH 2CH2NMe2)2]GaH3 (5) was obtained from the reaction of 1 with H3Al(NMe3) or 3 with H3Ga(NMe3), and a crystal consisting of a mixture of 5 and 2 was structurally characterized. The five-coordinate chloro derivative, Cl2Ga[N(CH2CH2NMe2)2] (6), was synthesized and characterized.",

author = "Bing Luo and Kucera, {Benjamin E.} and Gladfelter, {Wayne L}",

year = "2006",

doi = "10.1039/b607164c",

language = "English (US)",

pages = "4491--4498",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "37",

}

TY - JOUR

T1 - Hydrido and chloro gallium and aluminium complexes with the tridentate bis(2-dimethylaminoethyl)amide ligand

AU - Luo, Bing

AU - Kucera, Benjamin E.

AU - Gladfelter, Wayne L

PY - 2006

Y1 - 2006

N2 - Five-coordinate gallium and aluminium dihydrides, H2Ga[N(CH 2CH2NMe2)2] (1) and H 2Al[N(CH2CH2NMe2)2] (3), were synthesized and found to be volatile and thermally stable. 1 and 3 reacted with H3Ga(NMe3) and H3Al(NMe3), respectively, to form H2Ga[N(CH2CH2NMe 2)2]GaH3 (2) and H2Al[N(CH 2CH2NMe2)2]AlH3 (4), in which the amido nitrogen bridged between the MH2 and MH3 groups (M = Ga or Al). A mixed metal complex, H2Al[N(CH 2CH2NMe2)2]GaH3 (5) was obtained from the reaction of 1 with H3Al(NMe3) or 3 with H3Ga(NMe3), and a crystal consisting of a mixture of 5 and 2 was structurally characterized. The five-coordinate chloro derivative, Cl2Ga[N(CH2CH2NMe2)2] (6), was synthesized and characterized.

AB - Five-coordinate gallium and aluminium dihydrides, H2Ga[N(CH 2CH2NMe2)2] (1) and H 2Al[N(CH2CH2NMe2)2] (3), were synthesized and found to be volatile and thermally stable. 1 and 3 reacted with H3Ga(NMe3) and H3Al(NMe3), respectively, to form H2Ga[N(CH2CH2NMe 2)2]GaH3 (2) and H2Al[N(CH 2CH2NMe2)2]AlH3 (4), in which the amido nitrogen bridged between the MH2 and MH3 groups (M = Ga or Al). A mixed metal complex, H2Al[N(CH 2CH2NMe2)2]GaH3 (5) was obtained from the reaction of 1 with H3Al(NMe3) or 3 with H3Ga(NMe3), and a crystal consisting of a mixture of 5 and 2 was structurally characterized. The five-coordinate chloro derivative, Cl2Ga[N(CH2CH2NMe2)2] (6), was synthesized and characterized.

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U2 - 10.1039/b607164c

DO - 10.1039/b607164c

M3 - Article

C2 - 16981024

AN - SCOPUS:33748701505

SN - 1477-9226

SP - 4491

EP - 4498

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

Hydrido and chloro gallium and aluminium complexes with the tridentate bis(2-dimethylaminoethyl)amide ligand

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