H2 adsorption and ortho-para conversion on ETS-10

J. G. Vitillo, D. Cocina, E. N. Gribov, G. Ricchiardi, A. Zecchina, G. Spoto

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Adsorption of H2 at 20 K on (Na,K) ETS-10 is studied by means of infrared spectroscopy and molecular mechanics simulations. The occurrence of three steps is evidenced, consisting of: (i) specific interaction of H2 with extraframework cations; (ii) aspecific interaction with the channel walls and (iii) pore-filling by a liquid-like phase. Spectroscopic evidence is also given that (Na,K) ETS-10 promotes ortho-para conversion of the adsorbed H2 species.

Original languageEnglish (US)
Title of host publicationFrom Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
PublisherElsevier Inc.
Pages893-901
Number of pages9
EditionA
ISBN (Print)0444530681, 9780444530684
DOIs
StatePublished - Jan 1 2007

Publication series

NameStudies in Surface Science and Catalysis
NumberA
Volume170
ISSN (Print)0167-2991

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