Homogeneous Catalytic Carbonylation of Nitroaromatics. 9. Kinetics and Mechanism of the First N–O Bond Cleavage and Structure of the η2-ArNO Interme diate

Steven J. Skoog; John P. Campbell; Wayne L Gladfelter

doi:10.1021/om00023a005

Homogeneous Catalytic Carbonylation of Nitroaromatics. 9. Kinetics and Mechanism of the First N–O Bond Cleavage and Structure of the η²-ArNO Interme diate

Steven J. Skoog
, John P. Campbell
, Wayne L Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

The reaction between Ru(dppeXCO)₃ and ArNO₂ produced CO₂ and the new complex Ru(dppe)-(CO)₂(η²-ONAr), which was shown by X-ray crystallography to contain a π-bound nitrosoarene ligand. Kinetic studies using a variety of substituents on the nitroarene established that the reaction was first order in each reagent and were consistent with an electron-transfer process during the rate-determining step.

Original language	English (US)
Pages (from-to)	4137-4139
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	11
DOIs	https://doi.org/10.1021/om00023a005
State	Published - Nov 1 1994

Publisher link

10.1021/om00023a005

Find It

Find It at U of M Libraries

Cite this

@article{81ffd7df5734497487002eafd5400224,

title = "Homogeneous Catalytic Carbonylation of Nitroaromatics. 9. Kinetics and Mechanism of the First N–O Bond Cleavage and Structure of the η2-ArNO Interme diate",

abstract = "The reaction between Ru(dppeXCO)3 and ArNO2 produced CO2 and the new complex Ru(dppe)-(CO)2(η2-ONAr), which was shown by X-ray crystallography to contain a π-bound nitrosoarene ligand. Kinetic studies using a variety of substituents on the nitroarene established that the reaction was first order in each reagent and were consistent with an electron-transfer process during the rate-determining step.",

author = "Skoog, \{Steven J.\} and Campbell, \{John P.\} and Gladfelter, \{Wayne L\}",

year = "1994",

month = nov,

day = "1",

doi = "10.1021/om00023a005",

language = "English (US)",

volume = "13",

pages = "4137--4139",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Homogeneous Catalytic Carbonylation of Nitroaromatics. 9. Kinetics and Mechanism of the First N–O Bond Cleavage and Structure of the η2-ArNO Interme diate

AU - Skoog, Steven J.

AU - Campbell, John P.

AU - Gladfelter, Wayne L

PY - 1994/11/1

Y1 - 1994/11/1

N2 - The reaction between Ru(dppeXCO)3 and ArNO2 produced CO2 and the new complex Ru(dppe)-(CO)2(η2-ONAr), which was shown by X-ray crystallography to contain a π-bound nitrosoarene ligand. Kinetic studies using a variety of substituents on the nitroarene established that the reaction was first order in each reagent and were consistent with an electron-transfer process during the rate-determining step.

AB - The reaction between Ru(dppeXCO)3 and ArNO2 produced CO2 and the new complex Ru(dppe)-(CO)2(η2-ONAr), which was shown by X-ray crystallography to contain a π-bound nitrosoarene ligand. Kinetic studies using a variety of substituents on the nitroarene established that the reaction was first order in each reagent and were consistent with an electron-transfer process during the rate-determining step.

UR - https://www.scopus.com/pages/publications/0001562819

UR - https://www.scopus.com/pages/publications/0001562819#tab=citedBy

U2 - 10.1021/om00023a005

DO - 10.1021/om00023a005

M3 - Article

AN - SCOPUS:0001562819

SN - 0276-7333

VL - 13

SP - 4137

EP - 4139

JO - Organometallics

JF - Organometallics

IS - 11

ER -

Homogeneous Catalytic Carbonylation of Nitroaromatics. 9. Kinetics and Mechanism of the First N–O Bond Cleavage and Structure of the η²-ArNO Interme diate

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this