Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-

Giovanna Tripepi; Victor G. Young; John E. Ellis

doi:10.1016/S0022-328X(99)00551-3

Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-

Giovanna Tripepi, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)₄]^2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-, which has been structurally characterized as the [K(18-crown-6)]⁺ salt.

Original language	English (US)
Pages (from-to)	354-360
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	593-594
DOIs	https://doi.org/10.1016/S0022-328X(99)00551-3
State	Published - Jan 15 2000

Keywords

Azobenzene
Carbonyl
Hydroxo complexes
Titanium

Access

10.1016/S0022-328X(99)00551-3

Fingerprint Dive into the research topics of 'Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-'. Together they form a unique fingerprint.

Cite this

Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-. / Tripepi, Giovanna; Young, Victor G.; Ellis, John E.

In: Journal of Organometallic Chemistry, Vol. 593-594, 15.01.2000, p. 354-360.

Research output: Contribution to journal › Article › peer-review

@article{fd3b62a6661a46cc9a72065b3cbdae62,

title = "Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-",

abstract = "Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.",

keywords = "Azobenzene, Carbonyl, Hydroxo complexes, Titanium",

author = "Giovanna Tripepi and Young, {Victor G.} and Ellis, {John E.}",

year = "2000",

month = jan,

day = "15",

doi = "10.1016/S0022-328X(99)00551-3",

language = "English (US)",

volume = "593-594",

pages = "354--360",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-

AU - Tripepi, Giovanna

AU - Young, Victor G.

AU - Ellis, John E.

PY - 2000/1/15

Y1 - 2000/1/15

N2 - Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.

AB - Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.

KW - Azobenzene

KW - Carbonyl

KW - Hydroxo complexes

KW - Titanium

UR - http://www.scopus.com/inward/record.url?scp=0034649918&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034649918&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(99)00551-3

DO - 10.1016/S0022-328X(99)00551-3

M3 - Article

AN - SCOPUS:0034649918

VL - 593-594

SP - 354

EP - 360

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -