Abstract
Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.
Original language | English (US) |
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Pages (from-to) | 354-360 |
Number of pages | 7 |
Journal | Journal of Organometallic Chemistry |
Volume | 593-594 |
DOIs | |
State | Published - Jan 15 2000 |
Keywords
- Azobenzene
- Carbonyl
- Hydroxo complexes
- Titanium