Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-

Giovanna Tripepi; Victor G. Young; John E. Ellis

doi:10.1016/S0022-328X(99)00551-3

Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-

Giovanna Tripepi, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)₄]^2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-, which has been structurally characterized as the [K(18-crown-6)]⁺ salt.

Original language	English (US)
Pages (from-to)	354-360
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	593-594
DOIs	https://doi.org/10.1016/S0022-328X(99)00551-3
State	Published - Jan 15 2000

Bibliographical note

Funding Information:
The authors wish to thank the US National Science Foundation and the donors of the Petroleum Research Fund administered by the American Chemical Society for financial support and the Scuola Normale Superiore, Pisa, Italy, and the Petroleum Research Fund for fellowships to G.T. We also thank Christine Lundby for her expert assistant with the manuscript and Professor Rinaldo Poli for his invitation to contribute to this volume.

Keywords

Azobenzene
Carbonyl
Hydroxo complexes
Titanium

Access

10.1016/S0022-328X(99)00551-3

Fingerprint

Dive into the research topics of 'Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-'. Together they form a unique fingerprint.

Cite this

Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti₂(μ-OH)₂(CO)₈]^2-. / Tripepi, Giovanna; Young, Victor G.; Ellis, John E.

In: Journal of Organometallic Chemistry, Vol. 593-594, 15.01.2000, p. 354-360.

Research output: Contribution to journal › Article › peer-review

@article{fd3b62a6661a46cc9a72065b3cbdae62,

title = "Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-",

abstract = "Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.",

keywords = "Azobenzene, Carbonyl, Hydroxo complexes, Titanium",

author = "Giovanna Tripepi and Young, {Victor G.} and Ellis, {John E.}",

note = "Funding Information: The authors wish to thank the US National Science Foundation and the donors of the Petroleum Research Fund administered by the American Chemical Society for financial support and the Scuola Normale Superiore, Pisa, Italy, and the Petroleum Research Fund for fellowships to G.T. We also thank Christine Lundby for her expert assistant with the manuscript and Professor Rinaldo Poli for his invitation to contribute to this volume.",

year = "2000",

month = jan,

day = "15",

doi = "10.1016/S0022-328X(99)00551-3",

language = "English (US)",

volume = "593-594",

pages = "354--360",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Highly reduced organometallics Part 49. Reaction of hexacarbonyltitanate(2-) with azobenzene. Structural characterization of the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-

AU - Tripepi, Giovanna

AU - Young, Victor G.

AU - Ellis, John E.

N1 - Funding Information: The authors wish to thank the US National Science Foundation and the donors of the Petroleum Research Fund administered by the American Chemical Society for financial support and the Scuola Normale Superiore, Pisa, Italy, and the Petroleum Research Fund for fellowships to G.T. We also thank Christine Lundby for her expert assistant with the manuscript and Professor Rinaldo Poli for his invitation to contribute to this volume.

PY - 2000/1/15

Y1 - 2000/1/15

N2 - Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.

AB - Hexacarbonyltitanate(2-) reacts with azobenzene to provide 40-65% yields of [Ti(PhNNPh)(CO)4]2-, which is formulated as a 1,2-diphenylhydrazido dianion adduct of zerovalent titanium tetracarbonyl. The latter undergoes very facile hydrolysis to provide 1,2-diphenylhydrazine and the first hydroxo-carbonyl of titanium [Ti2(μ-OH)2(CO)8]2-, which has been structurally characterized as the [K(18-crown-6)]+ salt.

KW - Azobenzene

KW - Carbonyl

KW - Hydroxo complexes

KW - Titanium

UR - http://www.scopus.com/inward/record.url?scp=0034649918&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034649918&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(99)00551-3

DO - 10.1016/S0022-328X(99)00551-3

M3 - Article

AN - SCOPUS:0034649918

VL - 593-594

SP - 354

EP - 360

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -