Highly reduced organometallics 42. A new method for the syntheses of [V(CO)6]- and [V(PF3)6]-involving anthracenide mediated reductions of VCl3(THF)3

Mikhail V. Barybin; Marie K. Pomije; John E. Ellis

doi:10.1016/S0020-1693(97)05771-X

Highly reduced organometallics 42. A new method for the syntheses of [V(CO)₆]^- and [V(PF₃)₆]-involving anthracenide mediated reductions of VCl₃(THF)₃

Mikhail V. Barybin, Marie K. Pomije, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)₆]^- by the sodium anthracenide mediated reductive carbonylation of VCl₃(THF)₃ is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF₃)₆]^-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.

Original language	English (US)
Pages (from-to)	58-62
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	269
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(97)05771-X
State	Published - Mar 3 1998

Bibliographical note

Funding Information:
We dedicate this article to Professor Dr Wolfgang Beck on the occasion of his 65th birthday. J.E.E. also wishes to thank him for his friendship, support and inspiration throughout the years. The National Science Foundation and the donors of the Petroleum Research Fund, admi,fistered by the American Chemical Society, provided financial support for these studies. We thank Christine Lundby for her expert assistance in the preparation of the manuscript and Professor Dr H. N0th and Priv. Doz. Dr W. Wcigand for their invitation to contribute to this special volume.

Keywords

Anion complexes
Carbonyl complexes
Trifluorophosphine complexes
Vanadium complexes

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title = "Highly reduced organometallics 42. A new method for the syntheses of [V(CO)6]- and [V(PF3)6]-involving anthracenide mediated reductions of VCl3(THF)3",

abstract = "A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)6]- by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)3 is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)6]-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.",

keywords = "Anion complexes, Carbonyl complexes, Trifluorophosphine complexes, Vanadium complexes",

author = "Barybin, {Mikhail V.} and Pomije, {Marie K.} and Ellis, {John E.}",

note = "Funding Information: We dedicate this article to Professor Dr Wolfgang Beck on the occasion of his 65th birthday. J.E.E. also wishes to thank him for his friendship, support and inspiration throughout the years. The National Science Foundation and the donors of the Petroleum Research Fund, admi,fistered by the American Chemical Society, provided financial support for these studies. We thank Christine Lundby for her expert assistance in the preparation of the manuscript and Professor Dr H. N0th and Priv. Doz. Dr W. Wcigand for their invitation to contribute to this special volume.",

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AU - Pomije, Marie K.

AU - Ellis, John E.

N1 - Funding Information: We dedicate this article to Professor Dr Wolfgang Beck on the occasion of his 65th birthday. J.E.E. also wishes to thank him for his friendship, support and inspiration throughout the years. The National Science Foundation and the donors of the Petroleum Research Fund, admi,fistered by the American Chemical Society, provided financial support for these studies. We thank Christine Lundby for her expert assistance in the preparation of the manuscript and Professor Dr H. N0th and Priv. Doz. Dr W. Wcigand for their invitation to contribute to this special volume.

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N2 - A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)6]- by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)3 is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)6]-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.

AB - A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)6]- by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)3 is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)6]-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.

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KW - Carbonyl complexes

KW - Trifluorophosphine complexes

KW - Vanadium complexes

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