Highly reduced organometallics 42. A new method for the syntheses of [V(CO)6]- and [V(PF3)6]-involving anthracenide mediated reductions of VCl3(THF)3

Mikhail V. Barybin; Marie K. Pomije; John E. Ellis

doi:10.1016/S0020-1693(97)05771-X

Highly reduced organometallics 42. A new method for the syntheses of [V(CO)₆]^- and [V(PF₃)₆]-involving anthracenide mediated reductions of VCl₃(THF)₃

Mikhail V. Barybin, Marie K. Pomije, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)₆]^- by the sodium anthracenide mediated reductive carbonylation of VCl₃(THF)₃ is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF₃)₆]^-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.

Original language	English (US)
Pages (from-to)	58-62
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	269
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(97)05771-X
State	Published - Mar 3 1998

Keywords

Anion complexes
Carbonyl complexes
Trifluorophosphine complexes
Vanadium complexes

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10.1016/S0020-1693(97)05771-X

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abstract = "A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)6]- by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)3 is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)6]-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.",

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AU - Pomije, Marie K.

AU - Ellis, John E.

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AB - A new mild (0°C, 1 atm P) and high yield (70%) synthesis of [V(CO)6]- by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)3 is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)6]-, a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates.

KW - Anion complexes

KW - Carbonyl complexes

KW - Trifluorophosphine complexes

KW - Vanadium complexes

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