(Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols.
|Original language||English (US)|
|Number of pages||4|
|State||Published - Aug 28 2006|
Bibliographical noteFunding Information:
The authors gratefully acknowledge the National Science Foundation for support of this work through research Grant (CHE 0353541), NSF-MRI award (CHE 0416157) and University of Ulsan Research Fund 2006.
- Hypervalent iodine