High-valent transition metal arene complexes: Investigation of the mesitylene complex of TiCl3+

Paul Kiprof, Carl N. Sandness, Anthony J. LePine, Jason A. Kallestad, Alexey Y. Koposov, Victor G Young

Research output: Contribution to journalArticlepeer-review

Abstract

The solution and solid-state structure of [(mesitylene)TiCl3][AlCl4], a rare example of a high-valent transition metal arene complex, was investigated experimentally and through theoretical calculations.

Original languageEnglish (US)
Pages (from-to)4847-4850
Number of pages4
JournalInorganica Chimica Acta
Volume359
Issue number15
DOIs
StatePublished - Dec 1 2006

Keywords

  • Ab initio
  • Arene complexes
  • DFT
  • Fluctionality
  • Mesitylene complexes
  • Titanium complexes

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