High-valent transition metal arene complexes: Investigation of the mesitylene complex of TiCl3+

Paul Kiprof; Carl N. Sandness; Anthony J. LePine; Jason A. Kallestad; Alexey Y. Koposov; Victor G Young

doi:10.1016/j.ica.2006.07.069

High-valent transition metal arene complexes: Investigation of the mesitylene complex of TiCl₃⁺

Paul Kiprof, Carl N. Sandness, Anthony J. LePine, Jason A. Kallestad, Alexey Y. Koposov, Victor G Young

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The solution and solid-state structure of [(mesitylene)TiCl₃][AlCl₄], a rare example of a high-valent transition metal arene complex, was investigated experimentally and through theoretical calculations.

Original language	English (US)
Pages (from-to)	4847-4850
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	359
Issue number	15
DOIs	https://doi.org/10.1016/j.ica.2006.07.069
State	Published - Dec 1 2006

Keywords

Ab initio
Arene complexes
DFT
Fluctionality
Mesitylene complexes
Titanium complexes

Publisher link

10.1016/j.ica.2006.07.069

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title = "High-valent transition metal arene complexes: Investigation of the mesitylene complex of TiCl3+",

abstract = "The solution and solid-state structure of [(mesitylene)TiCl3][AlCl4], a rare example of a high-valent transition metal arene complex, was investigated experimentally and through theoretical calculations.",

keywords = "Ab initio, Arene complexes, DFT, Fluctionality, Mesitylene complexes, Titanium complexes",

author = "Paul Kiprof and Sandness, {Carl N.} and LePine, {Anthony J.} and Kallestad, {Jason A.} and Koposov, {Alexey Y.} and Young, {Victor G}",

year = "2006",

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T1 - High-valent transition metal arene complexes

T2 - Investigation of the mesitylene complex of TiCl3+

AU - Kiprof, Paul

AU - Sandness, Carl N.

AU - LePine, Anthony J.

AU - Kallestad, Jason A.

AU - Koposov, Alexey Y.

AU - Young, Victor G

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The solution and solid-state structure of [(mesitylene)TiCl3][AlCl4], a rare example of a high-valent transition metal arene complex, was investigated experimentally and through theoretical calculations.

AB - The solution and solid-state structure of [(mesitylene)TiCl3][AlCl4], a rare example of a high-valent transition metal arene complex, was investigated experimentally and through theoretical calculations.

KW - Ab initio

KW - Arene complexes

KW - DFT

KW - Fluctionality

KW - Mesitylene complexes

KW - Titanium complexes

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