High-valent iron-mediated cis-hydroxyacetoxylation of olefins

Lawrence Que, Ruben Mas-Balleste, Megumi Fujita

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H2O 2 that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)Fe V(O)(OAc)]2+ oxidant.

Original languageEnglish (US)
Pages (from-to)1828-1830
Number of pages3
JournalDalton Transactions
Issue number14
DOIs
StatePublished - 2008

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