High-valent iron-mediated cis-hydroxyacetoxylation of olefins

Lawrence Que; Ruben Mas-Balleste; Megumi Fujita

doi:10.1039/b802587h

High-valent iron-mediated cis-hydroxyacetoxylation of olefins

Lawrence Que, Ruben Mas-Balleste, Megumi Fujita

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H₂O ₂ that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)Fe ^V(O)(OAc)]²⁺ oxidant.

Original language	English (US)
Pages (from-to)	1828-1830
Number of pages	3
Journal	Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/b802587h
State	Published - 2008

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10.1039/b802587h

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title = "High-valent iron-mediated cis-hydroxyacetoxylation of olefins",

abstract = "Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H2O 2 that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)Fe V(O)(OAc)]2+ oxidant.",

author = "Lawrence Que and Ruben Mas-Balleste and Megumi Fujita",

year = "2008",

doi = "10.1039/b802587h",

language = "English (US)",

pages = "1828--1830",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - High-valent iron-mediated cis-hydroxyacetoxylation of olefins

AU - Que, Lawrence

AU - Mas-Balleste, Ruben

AU - Fujita, Megumi

PY - 2008

Y1 - 2008

N2 - Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H2O 2 that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)Fe V(O)(OAc)]2+ oxidant.

AB - Evidence is obtained for the unprecedented cis-1,2-hydroxy-acetoxylation of olefins as minor products of the epoxidation of olefins by H2O 2 that is catalyzed by nonheme iron complexes in the presence of acetic acid, providing further support for the previously proposed [(TPA)Fe V(O)(OAc)]2+ oxidant.

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DO - 10.1039/b802587h

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EP - 1830

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

High-valent iron-mediated cis-hydroxyacetoxylation of olefins

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