High resolution vibration-rotation spectrum of the D2O molecule in the region near the 2v1 + v2 + v3 absorption band

Jing Jing Zheng; O. N. Ulenikov; G. A. Onopenko; E. S. Bekhtereva; Sheng Gui He; Xiang Huai Wang; Shui Ming Hu; Hai Lin; Qing Shi Zhu

doi:10.1080/00268970010028854

High resolution vibration-rotation spectrum of the D₂O molecule in the region near the 2v₁ + v₂ + v₃ absorption band

Jing Jing Zheng, O. N. Ulenikov, G. A. Onopenko, E. S. Bekhtereva, Sheng Gui He, Xiang Huai Wang, Shui Ming Hu, Hai Lin, Qing Shi Zhu

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The high resolution Fourier transform spectrum of the D₂O (v = v₁ + v₂/2 + v₃ = 3.5) polyad was analysed within the framework of the Hamiltonian model taking into account resonance interactions between the seven states (310), (211), (112), (013), (230), (131) and (032). Transitions belonging to the 2v₁ + v₂ + v₃, 3v₁ + v₂ and 3v₂ + 2v₃ bands were assigned in the experimentally recorded spectrum. This provided the possibility of obtaining spectroscopic parameters of the 'visible' states (211), (310) and (032) and of estimating the band centres, and the rotational and resonance interaction parameters of the 'dark' states (112) and (131).

Original language	English (US)
Pages (from-to)	931-937
Number of pages	7
Journal	Molecular Physics
Volume	99
Issue number	11
DOIs	https://doi.org/10.1080/00268970010028854
State	Published - Jun 10 2001

Bibliographical note

Funding Information:
This work is jointly supported by the National Natural Science Foundation of China (Grant No. 29892161) and the Program of ‘climbing’ of China. O.U. thanks the University of Science and Technology of China for a guest professorship, and G.O. thanks the Ru Jia-xi

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10.1080/00268970010028854

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@article{f0c5ba151cfb4ac8a65a9b7602d0145d,

title = "High resolution vibration-rotation spectrum of the D2O molecule in the region near the 2v1 + v2 + v3 absorption band",

abstract = "The high resolution Fourier transform spectrum of the D2O (v = v1 + v2/2 + v3 = 3.5) polyad was analysed within the framework of the Hamiltonian model taking into account resonance interactions between the seven states (310), (211), (112), (013), (230), (131) and (032). Transitions belonging to the 2v1 + v2 + v3, 3v1 + v2 and 3v2 + 2v3 bands were assigned in the experimentally recorded spectrum. This provided the possibility of obtaining spectroscopic parameters of the 'visible' states (211), (310) and (032) and of estimating the band centres, and the rotational and resonance interaction parameters of the 'dark' states (112) and (131).",

author = "Zheng, {Jing Jing} and Ulenikov, {O. N.} and Onopenko, {G. A.} and Bekhtereva, {E. S.} and He, {Sheng Gui} and Wang, {Xiang Huai} and Hu, {Shui Ming} and Hai Lin and Zhu, {Qing Shi}",

note = "Funding Information: This work is jointly supported by the National Natural Science Foundation of China (Grant No. 29892161) and the Program of {\textquoteleft}climbing{\textquoteright} of China. O.U. thanks the University of Science and Technology of China for a guest professorship, and G.O. thanks the Ru Jia-xi",

year = "2001",

month = jun,

day = "10",

doi = "10.1080/00268970010028854",

language = "English (US)",

volume = "99",

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journal = "Molecular Physics",

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TY - JOUR

T1 - High resolution vibration-rotation spectrum of the D2O molecule in the region near the 2v1 + v2 + v3 absorption band

AU - Zheng, Jing Jing

AU - Ulenikov, O. N.

AU - Onopenko, G. A.

AU - Bekhtereva, E. S.

AU - He, Sheng Gui

AU - Wang, Xiang Huai

AU - Hu, Shui Ming

AU - Lin, Hai

AU - Zhu, Qing Shi

N1 - Funding Information: This work is jointly supported by the National Natural Science Foundation of China (Grant No. 29892161) and the Program of ‘climbing’ of China. O.U. thanks the University of Science and Technology of China for a guest professorship, and G.O. thanks the Ru Jia-xi

PY - 2001/6/10

Y1 - 2001/6/10

N2 - The high resolution Fourier transform spectrum of the D2O (v = v1 + v2/2 + v3 = 3.5) polyad was analysed within the framework of the Hamiltonian model taking into account resonance interactions between the seven states (310), (211), (112), (013), (230), (131) and (032). Transitions belonging to the 2v1 + v2 + v3, 3v1 + v2 and 3v2 + 2v3 bands were assigned in the experimentally recorded spectrum. This provided the possibility of obtaining spectroscopic parameters of the 'visible' states (211), (310) and (032) and of estimating the band centres, and the rotational and resonance interaction parameters of the 'dark' states (112) and (131).

AB - The high resolution Fourier transform spectrum of the D2O (v = v1 + v2/2 + v3 = 3.5) polyad was analysed within the framework of the Hamiltonian model taking into account resonance interactions between the seven states (310), (211), (112), (013), (230), (131) and (032). Transitions belonging to the 2v1 + v2 + v3, 3v1 + v2 and 3v2 + 2v3 bands were assigned in the experimentally recorded spectrum. This provided the possibility of obtaining spectroscopic parameters of the 'visible' states (211), (310) and (032) and of estimating the band centres, and the rotational and resonance interaction parameters of the 'dark' states (112) and (131).

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