High-resolution spectrum of the v1 + v4(E), v3 + v4(E), v3 + v4(A1), and v3 + v4(A2) bands of the PH3 molecule: Assignments and preliminary analysis

O. N. Ulenikov, E. S. Bekhtereva, V. A. Kozinskaia, Jing Jing Zheng, Sheng Gui He, Shui Ming Hu, Qing Shi Zhu, C. Leroy, L. Pluchart

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Abstract

The high-resolution (0.005 cm-1) Fourier transform infrared spectrum of PH3 is recorded in the region between 3280 and 3580 cm-1 where the following bands are located: v1 + v4(E), v3 + v4(E), v3 + v4(A1), forbidden on symmetry band v3 + v4(A2), and very weak bands v1 + v2(A1), v2 + v3(E). Transitions are assigned to the first four ones. Vibrational analysis of known experimental data is made.

Original languageEnglish (US)
Pages (from-to)599-618
Number of pages20
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume83
Issue number3-4
StatePublished - Feb 1 2004

Keywords

  • PH molecule
  • Vibrational-rotational spectra

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    Ulenikov, O. N., Bekhtereva, E. S., Kozinskaia, V. A., Zheng, J. J., He, S. G., Hu, S. M., Zhu, Q. S., Leroy, C., & Pluchart, L. (2004). High-resolution spectrum of the v1 + v4(E), v3 + v4(E), v3 + v4(A1), and v3 + v4(A2) bands of the PH3 molecule: Assignments and preliminary analysis. Journal of Quantitative Spectroscopy and Radiative Transfer, 83(3-4), 599-618.