High-resolution analysis of the ν2+2ν3 band of HDO

Shui Ming Hu, Sheng Gui He, Jing Jing Zheng, Xiang Huai Wang, Yun Ding, Qing Shi Zhu

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The Fourier transform spectrum of the ν2+2ν3 band of the HDO molecule was recorded with a resolution of 0.02 cm-1. The spectrum was rotational analysed and the spectroscopic parameters of the (0,1,2) state were estimated in terms of Watson's effective rotational Hamiltonian model and also the model in the Padé-Borel approximation form. They reproduce the upper energy levels with an accuracy close to the experimental uncertainty of 0.001 cm-1.

Original languageEnglish (US)
Pages (from-to)1021-1027
Number of pages7
JournalChinese Physics
Volume10
Issue number11
DOIs
StatePublished - Dec 1 2001

Keywords

  • Fourier transform spectroscopy
  • HDO molecule
  • ro-vibrational spectrum

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