Helical nanofilament phases

L. E. Hough, H. T. Jung, D. Krüerke, M. S. Heberling, M. Nakata, C. D. Jones, D. Chen, D. R. Link, J. Zasadzinski, G. Heppke, J. P. Rabe, W. Stocker, E. Körblova, D. M. Walba, M. A. Glaser, N. A. Clark

Research output: Contribution to journalArticle

206 Scopus citations

Abstract

In the formation of chiral crystals, the tendency for twist in the orientation of neighboring molecules is incompatible with ordering into a lattice: Twist is expelled from planar layers at the expense of local strain. We report the ordered state of a neat material in which a local chiral structure is expressed as twisted layers, a state made possible by spatial limitation of layering to a periodic array of nanoscale filaments. Although made of achiral molecules, the layers in these filaments are twisted and rigorously homochiral - a broken symmetry. The precise structural definition achieved in filament self-assembly enables collective organization into arrays in which an additional broken symmetry - the appearance of macroscopic coherence of the filament twist-produces a liquid crystal phase of helically precessing layers.

Original languageEnglish (US)
Pages (from-to)456-460
Number of pages5
JournalScience
Volume325
Issue number5939
DOIs
StatePublished - Jul 24 2009

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    Hough, L. E., Jung, H. T., Krüerke, D., Heberling, M. S., Nakata, M., Jones, C. D., Chen, D., Link, D. R., Zasadzinski, J., Heppke, G., Rabe, J. P., Stocker, W., Körblova, E., Walba, D. M., Glaser, M. A., & Clark, N. A. (2009). Helical nanofilament phases. Science, 325(5939), 456-460. https://doi.org/10.1126/science.1170027