Graphene acoustic plasmon resonator for ultrasensitive infrared spectroscopy

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7 Citations (Scopus)

Abstract

One of the fundamental hurdles in plasmonics is the trade-off between electromagnetic field confinement and the coupling efficiency with free-space light, a consequence of the large momentum mismatch between the excitation source and plasmonic modes. Acoustic plasmons in graphene, in particular, have an extreme level of field confinement, as well as an extreme momentum mismatch. Here, we show that this fundamental compromise can be overcome and demonstrate a graphene acoustic plasmon resonator with nearly perfect absorption (94%) of incident mid-infrared light. This high efficiency is achieved by utilizing a two-stage coupling scheme: free-space light coupled to conventional graphene plasmons, which then couple to ultraconfined acoustic plasmons. To realize this scheme, we transfer unpatterned large-area graphene onto template-stripped ultraflat metal ribbons. A monolithically integrated optical spacer and a reflector further boost the enhancement. We show that graphene acoustic plasmons allow ultrasensitive measurements of absorption bands and surface phonon modes in ångström-thick protein and SiO 2 layers, respectively. Our acoustic plasmon resonator platform is scalable and can harness the ultimate level of light–matter interactions for potential applications including spectroscopy, sensing, metasurfaces and optoelectronics.

Original languageEnglish (US)
JournalNature Nanotechnology
DOIs
StatePublished - Jan 1 2019

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Plasmons
Graphene
Resonators
Infrared spectroscopy
graphene
plasmons
Acoustics
resonators
infrared spectroscopy
acoustics
Momentum
momentum
harnesses
acceleration (physics)
Optoelectronic devices
Electromagnetic fields
spacers
ribbons
reflectors

How much support was provided by MRSEC?

  • Primary

Reporting period for MRSEC

  • Period 5

PubMed: MeSH publication types

  • Journal Article
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, Non-U.S. Gov't

Cite this

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title = "Graphene acoustic plasmon resonator for ultrasensitive infrared spectroscopy",
abstract = "One of the fundamental hurdles in plasmonics is the trade-off between electromagnetic field confinement and the coupling efficiency with free-space light, a consequence of the large momentum mismatch between the excitation source and plasmonic modes. Acoustic plasmons in graphene, in particular, have an extreme level of field confinement, as well as an extreme momentum mismatch. Here, we show that this fundamental compromise can be overcome and demonstrate a graphene acoustic plasmon resonator with nearly perfect absorption (94{\%}) of incident mid-infrared light. This high efficiency is achieved by utilizing a two-stage coupling scheme: free-space light coupled to conventional graphene plasmons, which then couple to ultraconfined acoustic plasmons. To realize this scheme, we transfer unpatterned large-area graphene onto template-stripped ultraflat metal ribbons. A monolithically integrated optical spacer and a reflector further boost the enhancement. We show that graphene acoustic plasmons allow ultrasensitive measurements of absorption bands and surface phonon modes in {\aa}ngstr{\"o}m-thick protein and SiO 2 layers, respectively. Our acoustic plasmon resonator platform is scalable and can harness the ultimate level of light–matter interactions for potential applications including spectroscopy, sensing, metasurfaces and optoelectronics.",
author = "In-Ho Lee and Daehan Yoo and Phaedon Avouris and Tony Low and Sang-Hyun Oh",
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AU - Yoo, Daehan

AU - Avouris, Phaedon

AU - Low, Tony

AU - Oh, Sang-Hyun

PY - 2019/1/1

Y1 - 2019/1/1

N2 - One of the fundamental hurdles in plasmonics is the trade-off between electromagnetic field confinement and the coupling efficiency with free-space light, a consequence of the large momentum mismatch between the excitation source and plasmonic modes. Acoustic plasmons in graphene, in particular, have an extreme level of field confinement, as well as an extreme momentum mismatch. Here, we show that this fundamental compromise can be overcome and demonstrate a graphene acoustic plasmon resonator with nearly perfect absorption (94%) of incident mid-infrared light. This high efficiency is achieved by utilizing a two-stage coupling scheme: free-space light coupled to conventional graphene plasmons, which then couple to ultraconfined acoustic plasmons. To realize this scheme, we transfer unpatterned large-area graphene onto template-stripped ultraflat metal ribbons. A monolithically integrated optical spacer and a reflector further boost the enhancement. We show that graphene acoustic plasmons allow ultrasensitive measurements of absorption bands and surface phonon modes in ångström-thick protein and SiO 2 layers, respectively. Our acoustic plasmon resonator platform is scalable and can harness the ultimate level of light–matter interactions for potential applications including spectroscopy, sensing, metasurfaces and optoelectronics.

AB - One of the fundamental hurdles in plasmonics is the trade-off between electromagnetic field confinement and the coupling efficiency with free-space light, a consequence of the large momentum mismatch between the excitation source and plasmonic modes. Acoustic plasmons in graphene, in particular, have an extreme level of field confinement, as well as an extreme momentum mismatch. Here, we show that this fundamental compromise can be overcome and demonstrate a graphene acoustic plasmon resonator with nearly perfect absorption (94%) of incident mid-infrared light. This high efficiency is achieved by utilizing a two-stage coupling scheme: free-space light coupled to conventional graphene plasmons, which then couple to ultraconfined acoustic plasmons. To realize this scheme, we transfer unpatterned large-area graphene onto template-stripped ultraflat metal ribbons. A monolithically integrated optical spacer and a reflector further boost the enhancement. We show that graphene acoustic plasmons allow ultrasensitive measurements of absorption bands and surface phonon modes in ångström-thick protein and SiO 2 layers, respectively. Our acoustic plasmon resonator platform is scalable and can harness the ultimate level of light–matter interactions for potential applications including spectroscopy, sensing, metasurfaces and optoelectronics.

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