Abstract
No solvent, no complications! The lithium acetylide ion, which is the monolithium salt of the carbide ion, was prepared in the gas phase (see scheme; CID=collisioninduced dissociation, ESI=electrospray ionization). Its reactivity and energetics are reported along with high-level computational results. (Figure Presented).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5161-5164 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 30 |
| DOIs | |
| State | Published - Jul 12 2010 |
Keywords
- Carbanions
- Computational chemistry
- Ion-molecule reactions
- Lithium acetylide
- Organolithium compounds