Gas chromatographic study of salvation enthalpy by solvatochromically based linear salvation energy relationships

Jianjun Li; Peter W. Carr

doi:10.1016/0021-9673(94)85079-8

Gas chromatographic study of salvation enthalpy by solvatochromically based linear salvation energy relationships

Jianjun Li, Peter W. Carr

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Solute retention in capillary GC columns can be correlated with a linear salvation energy relationship (LSER) equation using chromatographically determined solute parameters (log L¹⁶, π₂*,^C, α ₂^c and β₂^c. The LSER coefficients obtained from correlation studies serve to quantitatively characterize the stationary phase. The effect of column temperature on retention was characterized by the temperature dependence of the LSER coefficients. Enthalpy and entropy of the retention process were also fitted quite well to the LSER equation. The main contributions to retention are from the solute-solvent interactions that give large favorable enthalpies and small unfavorable entropies. The LSER coefficients for the free energy and enthalpy regressions are linearly correlated.

Original language	English (US)
Pages (from-to)	367-380
Number of pages	14
Journal	Journal of Chromatography A
Volume	659
Issue number	2
DOIs	https://doi.org/10.1016/0021-9673(94)85079-8
State	Published - Jan 28 1994

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title = "Gas chromatographic study of salvation enthalpy by solvatochromically based linear salvation energy relationships",

abstract = "Solute retention in capillary GC columns can be correlated with a linear salvation energy relationship (LSER) equation using chromatographically determined solute parameters (log L16, π2*,C, α 2c and β2c. The LSER coefficients obtained from correlation studies serve to quantitatively characterize the stationary phase. The effect of column temperature on retention was characterized by the temperature dependence of the LSER coefficients. Enthalpy and entropy of the retention process were also fitted quite well to the LSER equation. The main contributions to retention are from the solute-solvent interactions that give large favorable enthalpies and small unfavorable entropies. The LSER coefficients for the free energy and enthalpy regressions are linearly correlated.",

author = "Jianjun Li and Carr, {Peter W.}",

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AU - Li, Jianjun

AU - Carr, Peter W.

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N2 - Solute retention in capillary GC columns can be correlated with a linear salvation energy relationship (LSER) equation using chromatographically determined solute parameters (log L16, π2*,C, α 2c and β2c. The LSER coefficients obtained from correlation studies serve to quantitatively characterize the stationary phase. The effect of column temperature on retention was characterized by the temperature dependence of the LSER coefficients. Enthalpy and entropy of the retention process were also fitted quite well to the LSER equation. The main contributions to retention are from the solute-solvent interactions that give large favorable enthalpies and small unfavorable entropies. The LSER coefficients for the free energy and enthalpy regressions are linearly correlated.

AB - Solute retention in capillary GC columns can be correlated with a linear salvation energy relationship (LSER) equation using chromatographically determined solute parameters (log L16, π2*,C, α 2c and β2c. The LSER coefficients obtained from correlation studies serve to quantitatively characterize the stationary phase. The effect of column temperature on retention was characterized by the temperature dependence of the LSER coefficients. Enthalpy and entropy of the retention process were also fitted quite well to the LSER equation. The main contributions to retention are from the solute-solvent interactions that give large favorable enthalpies and small unfavorable entropies. The LSER coefficients for the free energy and enthalpy regressions are linearly correlated.

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