From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Timur Islamoglu, Debmalya Ray, Peng Li, Marek B. Majewski, Isil Akpinar, Xuan Zhang, Chris Cramer, Laura Gagliardi, Omar K. Farha

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

Original languageEnglish (US)
Pages (from-to)13246-13251
Number of pages6
JournalInorganic chemistry
Volume57
Issue number21
DOIs
StatePublished - Nov 5 2018

Bibliographical note

Funding Information:
O.K.F. acknowledges the support from the U.S. Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0003763 and Northwestern University for the experimental work. The theoretical work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE, Office of Basic Energy Sciences (DE-SC0012702). The computations were performed at the Minnesota Supercomputing Institute.

Publisher Copyright:
Copyright © 2018 American Chemical Society.

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