From Transition Metals to Lanthanides to Actinides

Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Timur Islamoglu, Debmalya Ray, Peng Li, Marek B. Majewski, Isil Akpinar, Xuan Zhang, Chris Cramer, Laura Gagliardi, Omar K. Farha

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

Original languageEnglish (US)
Pages (from-to)13246-13251
Number of pages6
JournalInorganic Chemistry
Volume57
Issue number21
DOIs
StatePublished - Nov 5 2018

Fingerprint

Actinoid Series Elements
Lanthanoid Series Elements
Electronic properties
Transition metals
metal oxides
Tuning
Metals
transition metals
tuning
Oxides
electronics
metals
Hydroxyl Radical
Stretching
shift

PubMed: MeSH publication types

  • Journal Article

Cite this

From Transition Metals to Lanthanides to Actinides : Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. / Islamoglu, Timur; Ray, Debmalya; Li, Peng; Majewski, Marek B.; Akpinar, Isil; Zhang, Xuan; Cramer, Chris; Gagliardi, Laura; Farha, Omar K.

In: Inorganic Chemistry, Vol. 57, No. 21, 05.11.2018, p. 13246-13251.

Research output: Contribution to journalArticle

Islamoglu, Timur ; Ray, Debmalya ; Li, Peng ; Majewski, Marek B. ; Akpinar, Isil ; Zhang, Xuan ; Cramer, Chris ; Gagliardi, Laura ; Farha, Omar K. / From Transition Metals to Lanthanides to Actinides : Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks. In: Inorganic Chemistry. 2018 ; Vol. 57, No. 21. pp. 13246-13251.
@article{5c8e32551feb417b9bd463ce314f009f,
title = "From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks",
abstract = "Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.",
author = "Timur Islamoglu and Debmalya Ray and Peng Li and Majewski, {Marek B.} and Isil Akpinar and Xuan Zhang and Chris Cramer and Laura Gagliardi and Farha, {Omar K.}",
year = "2018",
month = "11",
day = "5",
doi = "10.1021/acs.inorgchem.8b01748",
language = "English (US)",
volume = "57",
pages = "13246--13251",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "21",

}

TY - JOUR

T1 - From Transition Metals to Lanthanides to Actinides

T2 - Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

AU - Islamoglu, Timur

AU - Ray, Debmalya

AU - Li, Peng

AU - Majewski, Marek B.

AU - Akpinar, Isil

AU - Zhang, Xuan

AU - Cramer, Chris

AU - Gagliardi, Laura

AU - Farha, Omar K.

PY - 2018/11/5

Y1 - 2018/11/5

N2 - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

AB - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

UR - http://www.scopus.com/inward/record.url?scp=85054826000&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85054826000&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b01748

DO - 10.1021/acs.inorgchem.8b01748

M3 - Article

VL - 57

SP - 13246

EP - 13251

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 21

ER -