From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Timur Islamoglu, Debmalya Ray, Peng Li, Marek B. Majewski, Isil Akpinar, Xuan Zhang, Chris Cramer, Laura Gagliardi, Omar K. Farha

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

Original languageEnglish (US)
Pages (from-to)13246-13251
Number of pages6
JournalInorganic chemistry
Volume57
Issue number21
DOIs
StatePublished - Nov 5 2018

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