Frictional behavior of self-assembled polymer brushes

P. Schorr, S. M. Kilbey, M. Tirrell

Research output: Contribution to journalConference articlepeer-review

Abstract

The adsorption behavior and structural features of polystyrene (PS)-polyvinyl pyrollidone di- and tri-block copolymers in various solvent conditions were investigated. Normal forces were measured as a function of the separation distance between the brush-bearing surfaces while the layers were bathed in toluene. Following the friction forces measurements in the good solvent, the solvent was changed to cyclohexane, which was near-theta-solvent for PS brushes at 34.5 °C. Normal force and friction measurements were recorded in the near-theta solvent.

Original languageEnglish (US)
Pages (from-to)87-88
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume40
Issue number2
StatePublished - Aug 1999

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