Formation of the: Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII(η2-O2)(TMC)]+

Jai Prakash; Lawrence Que

doi:10.1039/c6cc01660j

Formation of the: Syn isomer of [Fe^IV(O_anti)(TMC)(NCMe)]²⁺ in the reaction of Lewis acids with the side-on bound peroxo ligand in [Fe^III(η²-O₂)(TMC)]⁺

Jai Prakash, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

We demonstrate that the reactions of [Fe^III(η²-O₂)(TMC)]⁺ (TMC = tetramethylcyclam) with Lewis acids (H⁺ and NO⁺) afford the recently described syn isomer of [Fe^IV(O)(TMC)(NCMe)]²⁺ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

Original language	English (US)
Pages (from-to)	8146-8148
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	52
DOIs	https://doi.org/10.1039/c6cc01660j
State	Published - 2016

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Publisher Copyright:
© 2016 The Royal Society of Chemistry.

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10.1039/c6cc01660j

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title = "Formation of the: Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII(η2-O2)(TMC)]+",

abstract = "We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.",

author = "Jai Prakash and Lawrence Que",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc01660j",

language = "English (US)",

volume = "52",

pages = "8146--8148",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T2 - Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII(η2-O2)(TMC)]+

AU - Prakash, Jai

AU - Que, Lawrence

PY - 2016

Y1 - 2016

N2 - We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

AB - We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

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U2 - 10.1039/c6cc01660j

DO - 10.1039/c6cc01660j

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JF - Chemical Communications

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