Formation of the: Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII2-O2)(TMC)]+

Jai Prakash, Larry Que

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2 Citations (Scopus)

Abstract

We demonstrate that the reactions of [FeIII2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

Original languageEnglish (US)
Pages (from-to)8146-8148
Number of pages3
JournalChemical Communications
Volume52
Issue number52
DOIs
StatePublished - Jan 1 2016

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title = "Formation of the: Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII(η2-O2)(TMC)]+",
abstract = "We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.",
author = "Jai Prakash and Larry Que",
year = "2016",
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doi = "10.1039/c6cc01660j",
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publisher = "Royal Society of Chemistry",
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T2 - Syn isomer of [FeIV(Oanti)(TMC)(NCMe)]2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [FeIII(η2-O2)(TMC)]+

AU - Prakash, Jai

AU - Que, Larry

PY - 2016/1/1

Y1 - 2016/1/1

N2 - We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

AB - We demonstrate that the reactions of [FeIII(η2-O2)(TMC)]+ (TMC = tetramethylcyclam) with Lewis acids (H+ and NO+) afford the recently described syn isomer of [FeIV(O)(TMC)(NCMe)]2+ (and not the anti isomer as had been tacitly assumed). This outcome is a logical consequence of the fact that the side-on peroxo ligand is bound to the syn face of the Fe(TMC) unit in the precursor.

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DO - 10.1039/c6cc01660j

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