Formation of Multilamellar Vesicles by Oscillatory Shear

Gerhard Fritz, Norman J. Wagner, Eric W. Kaler

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The formation of multilamellar vesicles (MLVs) from the lamellar phase of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in brine can be controlled by steady, oscillatory shearing. Increasing stress amplitude or decreasing frequency leads to more rapid onion formation. The formation kinetics can be scaled onto constant controlled shear stress experiments; this scaling demonstrates that a minimum strain amplitude of ∼14 that is independent of frequency is required for onion formation. Further, the ratio of deformation driving onion formation to the reversible, elastic deformation can be predicted from the loss tangent. The final size of the MLVs decreases with the stress amplitude, independent of frequency, in quantitative agreement with MLVs formed under steady, applied shear stress.

Original languageEnglish (US)
Pages (from-to)8709-8714
Number of pages6
JournalLangmuir
Volume19
Issue number21
DOIs
StatePublished - Oct 14 2003

Fingerprint Dive into the research topics of 'Formation of Multilamellar Vesicles by Oscillatory Shear'. Together they form a unique fingerprint.

Cite this