Flowing Afterglow Negative Ion Photoelectron Spectroscopy of Dirhenium: Evidence for Multiple Bonding in Re2 and Re2-

Doreen G. Leopold, W. C. Lineberger, Thomas M. Miller

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Although there is now an extensive spectroscopic literature concerning homonuclear diatomics of first-row transition metals, relatively little is known about dimers of the second and third transition series. Theoretical calculations for third-row systems predict more comparable (n + 1 )s and nd orbital sizes and energies than for their lighter congeners, due primarily to relativistic effects. This trend is expected to yield enhanced d-d bonding in third-row dimers, a prediction consistent with reported3 mass spectrometric dissociation energies. Spectroscopic confirmation of these predictions has not yet been possible, due to the nearly4 total lack of data for dimers of open d-shell third-row metal atoms.

Original languageEnglish (US)
Pages (from-to)178-179
Number of pages2
JournalJournal of the American Chemical Society
Volume108
Issue number1
DOIs
StatePublished - Jan 1 1986

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