First emission studies of Tc2X82- systems (X = Cl, Br)

Breeze N. Briggs; David R. McMillin; Tanya K. Todorova; Laura Gagliardi; Frederic Poineau; Kenneth R. Czerwinski; Alfred P. Sattelberger

doi:10.1039/c0dt00751j

First emission studies of Tc₂X₈^2- systems (X = Cl, Br)

Breeze N. Briggs
, David R. McMillin
, Tanya K. Todorova
, Laura Gagliardi
, Frederic Poineau
, Kenneth R. Czerwinski
, Alfred P. Sattelberger

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The emission spectra of the solids [n-Bu₄N]₂Tc ₂X₈ (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the ¹δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

Original language	English (US)
Pages (from-to)	11322-11324
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	47
DOIs	https://doi.org/10.1039/c0dt00751j
State	Published - Dec 21 2010

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10.1039/c0dt00751j

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title = "First emission studies of Tc2X82- systems (X = Cl, Br)",

abstract = "The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.",

author = "Briggs, \{Breeze N.\} and McMillin, \{David R.\} and Todorova, \{Tanya K.\} and Laura Gagliardi and Frederic Poineau and Czerwinski, \{Kenneth R.\} and Sattelberger, \{Alfred P.\}",

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doi = "10.1039/c0dt00751j",

language = "English (US)",

volume = "39",

pages = "11322--11324",

journal = "Dalton Transactions",

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TY - JOUR

T1 - First emission studies of Tc2X82- systems (X = Cl, Br)

AU - Briggs, Breeze N.

AU - McMillin, David R.

AU - Todorova, Tanya K.

AU - Gagliardi, Laura

AU - Poineau, Frederic

AU - Czerwinski, Kenneth R.

AU - Sattelberger, Alfred P.

PY - 2010/12/21

Y1 - 2010/12/21

N2 - The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

AB - The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

UR - https://www.scopus.com/pages/publications/78649341299

UR - https://www.scopus.com/pages/publications/78649341299#tab=citedBy

U2 - 10.1039/c0dt00751j

DO - 10.1039/c0dt00751j

M3 - Article

C2 - 21042603

AN - SCOPUS:78649341299

SN - 1477-9226

VL - 39

SP - 11322

EP - 11324

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

First emission studies of Tc₂X₈^2- systems (X = Cl, Br)

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