First emission studies of Tc2X82- systems (X = Cl, Br)

Breeze N. Briggs, David R. McMillin, Tanya K. Todorova, Laura Gagliardi, Frederic Poineau, Kenneth R. Czerwinski, Alfred P. Sattelberger

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The emission spectra of the solids [n-Bu4N]2Tc 2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

Original languageEnglish (US)
Pages (from-to)11322-11324
Number of pages3
JournalDalton Transactions
Volume39
Issue number47
DOIs
StatePublished - Dec 21 2010

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