Facile Incorporation of Bromine into Aromatic Systems under Conditions of Water Chlorination

Sechoing Lin; Marta T. Lukasewycz; Robert J. Llukkonen; Robert M. Carlson

doi:10.1021/es00130a018

Facile Incorporation of Bromine into Aromatic Systems under Conditions of Water Chlorination

Sechoing Lin, Marta T. Lukasewycz, Robert J. Llukkonen, Robert M. Carlson

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Abstract

The reaction of aqueous solutions of biphenyl and naphthalene with chlorine in the presence of potassium bromide resulted in the loss of organic substrate and the formation of a series of chlorinated and brominated products. The extent of the reaction in the presence of bromide was typically greater than with chlorine alone. Chloramine (pH >6.0) and chlorine dioxide (pH 4.5-7.5) in the presence or in the absence of bromide resulted in no substantial loss of biphenyl or naphthalene.

Original language	English (US)
Pages (from-to)	985-986
Number of pages	2
Journal	Environmental Science and Technology
Volume	18
Issue number	12
DOIs	https://doi.org/10.1021/es00130a018
State	Published - Dec 1984

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title = "Facile Incorporation of Bromine into Aromatic Systems under Conditions of Water Chlorination",

abstract = "The reaction of aqueous solutions of biphenyl and naphthalene with chlorine in the presence of potassium bromide resulted in the loss of organic substrate and the formation of a series of chlorinated and brominated products. The extent of the reaction in the presence of bromide was typically greater than with chlorine alone. Chloramine (pH >6.0) and chlorine dioxide (pH 4.5-7.5) in the presence or in the absence of bromide resulted in no substantial loss of biphenyl or naphthalene.",

author = "Sechoing Lin and Lukasewycz, {Marta T.} and Llukkonen, {Robert J.} and Carlson, {Robert M.}",

year = "1984",

month = dec,

doi = "10.1021/es00130a018",

language = "English (US)",

volume = "18",

pages = "985--986",

journal = "Environmental Science and Technology",

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T1 - Facile Incorporation of Bromine into Aromatic Systems under Conditions of Water Chlorination

AU - Lin, Sechoing

AU - Lukasewycz, Marta T.

AU - Llukkonen, Robert J.

AU - Carlson, Robert M.

PY - 1984/12

Y1 - 1984/12

N2 - The reaction of aqueous solutions of biphenyl and naphthalene with chlorine in the presence of potassium bromide resulted in the loss of organic substrate and the formation of a series of chlorinated and brominated products. The extent of the reaction in the presence of bromide was typically greater than with chlorine alone. Chloramine (pH >6.0) and chlorine dioxide (pH 4.5-7.5) in the presence or in the absence of bromide resulted in no substantial loss of biphenyl or naphthalene.

AB - The reaction of aqueous solutions of biphenyl and naphthalene with chlorine in the presence of potassium bromide resulted in the loss of organic substrate and the formation of a series of chlorinated and brominated products. The extent of the reaction in the presence of bromide was typically greater than with chlorine alone. Chloramine (pH >6.0) and chlorine dioxide (pH 4.5-7.5) in the presence or in the absence of bromide resulted in no substantial loss of biphenyl or naphthalene.

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