Abstract
The phenomenon of enthalpy-entropy compensation in gas chromatography is examined. Using 53 probe solutes that span a wide range in size (dispersive interaction), dipolarity, hydrogen-bond-donor and hydrogen-bond-acceptor strength, enthalpy-entropy compensation is not observed, while for probe solutes within a homologous series enthalpy-entropy compensation is observed as predicted by the linear salvation energy relationship methodology.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 105-116 |
| Number of pages | 12 |
| Journal | Journal of Chromatography A |
| Volume | 670 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - Jun 3 1994 |
Bibliographical note
Funding Information:This work was supportedi n part by grants to the University of Minnesota from the National ScienceF oundation and the Petroleum Research Foundation.