Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

Kui Chen, Lawrence Que

Research output: Contribution to journalArticlepeer-review

191 Scopus citations

Abstract

The incorporation of 18O from H218O into the product of stereospecific alkane hydroxylation by [Fe(II)(bpmen)-(CH3CN)2](ClO4)2-H2O2 provides the first strong evidence for the participation of a high-valent iron-ore species in the mechanism of a non-heme iron catalyst.

Original languageEnglish (US)
Pages (from-to)1375-1376
Number of pages2
JournalChemical Communications
Issue number15
DOIs
StatePublished - Aug 7 1999

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