Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

Kui Chen; Lawrence Que

doi:10.1039/a901678c

Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

Kui Chen, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

208 Scopus citations

Abstract

The incorporation of ¹⁸O from H₂¹⁸O into the product of stereospecific alkane hydroxylation by [Fe(II)(bpmen)-(CH₃CN)₂](ClO₄)₂-H₂O₂ provides the first strong evidence for the participation of a high-valent iron-ore species in the mechanism of a non-heme iron catalyst.

Original language	English (US)
Pages (from-to)	1375-1376
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/a901678c
State	Published - Aug 7 1999

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10.1039/a901678c

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title = "Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst",

abstract = "The incorporation of 18O from H218O into the product of stereospecific alkane hydroxylation by [Fe(II)(bpmen)-(CH3CN)2](ClO4)2-H2O2 provides the first strong evidence for the participation of a high-valent iron-ore species in the mechanism of a non-heme iron catalyst.",

author = "Kui Chen and Lawrence Que",

year = "1999",

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doi = "10.1039/a901678c",

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journal = "Chemical Communications",

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AU - Chen, Kui

AU - Que, Lawrence

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Y1 - 1999/8/7

N2 - The incorporation of 18O from H218O into the product of stereospecific alkane hydroxylation by [Fe(II)(bpmen)-(CH3CN)2](ClO4)2-H2O2 provides the first strong evidence for the participation of a high-valent iron-ore species in the mechanism of a non-heme iron catalyst.

AB - The incorporation of 18O from H218O into the product of stereospecific alkane hydroxylation by [Fe(II)(bpmen)-(CH3CN)2](ClO4)2-H2O2 provides the first strong evidence for the participation of a high-valent iron-ore species in the mechanism of a non-heme iron catalyst.

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JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Evidence for the participation of a high-valent iron-oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

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