Evaluation of diffusion for inorganic-nitrogen analysis of natural water and wastewater

S. A. Khan, R. L. Mulvaney, K. Strle, B. P. Horgan

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Public concern that agricultural use of N fertilizers may have adverse effects on environmental quality and human health has led to a growing need for reliable data concerning the concentration of inorganic N in ground and surface water. A study was conducted to compare the accuracy and precision of simple Mason-jar diffusion methods for quantitative determination of NH 4 / + and NO 3 / - in a wide variety of water and wastewater, relative to colorimetry, ion-selective potentiometry, and steam distillation. Good agreement among methods was generally obtained with standard solutions prepared using deionized water; however, substantial differences often were observed with natural and anthropogenic samples, because of either Cl - interference in measurements with the NO 3 / - electrode or CO 3 / 2- interference in distillation. Analytical accuracy also was evaluated by measuring recovery of N added as (NH 4 ) 2 SO 4 or KNO 3 (6 mg N L -1 ). With most of the samples studied, quantitative recovery (97-103%) was not achieved by potentiometry or distillation. Quantitative recoveries usually were achieved by a manual Berthelot method for colorimetric determination of NH 4 / + , whereas recovery was often incomplete when NO 3 / - analyses were performed with an automated flow-injection system using Cd 2+ reduction. Regardless of the sample matrix, diffusion was always accurate in measuring recovery of NH 4 / + or NO 3 / - .

Original languageEnglish (US)
Pages (from-to)1890-1895
Number of pages6
JournalJournal of Environmental Quality
Volume29
Issue number6
DOIs
StatePublished - Jan 1 2000

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